TY - JOUR
T1 - Polarographic study of the selenocyanate complexes of zinc and cadmium
AU - Humffray, A. A.
AU - Bond, A. M.
AU - Forrest, J. S.
PY - 1967
Y1 - 1967
N2 - Polarographic measurements on aqueous solutions containing cadmium and selenocyanate ions have shown the existence of the species CdCNSe+, Cd(CNSe)2, Cd(CNSe)3- and Cd(CNSe)42-, with stability constants (at ionic strength 2.0) of 20, 100, 440 and 1000, respectively. Under similar conditions for mixtures of zinc and selenocyanate ions, only two species, ZnCNSe+ and Zn(CNSe)2, are found, with stability constants (at ionic strength 2.0) of 5.8 and 10, respectively.
AB - Polarographic measurements on aqueous solutions containing cadmium and selenocyanate ions have shown the existence of the species CdCNSe+, Cd(CNSe)2, Cd(CNSe)3- and Cd(CNSe)42-, with stability constants (at ionic strength 2.0) of 20, 100, 440 and 1000, respectively. Under similar conditions for mixtures of zinc and selenocyanate ions, only two species, ZnCNSe+ and Zn(CNSe)2, are found, with stability constants (at ionic strength 2.0) of 5.8 and 10, respectively.
UR - http://www.scopus.com/inward/record.url?scp=0642367001&partnerID=8YFLogxK
U2 - 10.1016/0022-0728(67)85009-5
DO - 10.1016/0022-0728(67)85009-5
M3 - Article
AN - SCOPUS:0642367001
SN - 0022-0728
VL - 15
SP - 67
EP - 71
JO - Journal of Electroanalytical Chemistry and Interfacial Electrochemistry
JF - Journal of Electroanalytical Chemistry and Interfacial Electrochemistry
IS - C
ER -