Photomediated controlled radical polymerization

Xiangcheng Pan; Mehmet Atilla Tasdelen; Joachim Laun; Thomas Junkers; Yusuf Yagci; Krzysztof Matyjaszewski

doi:10.1016/j.progpolymsci.2016.06.005

Photomediated controlled radical polymerization

Xiangcheng Pan, Mehmet Atilla Tasdelen, Joachim Laun, Thomas Junkers, Yusuf Yagci, Krzysztof Matyjaszewski

Research output: Contribution to journal › Review Article › Research › peer-review

588 Citations (Scopus)

Abstract

Photomediated controlled radical polymerization is a versatile method to prepare, under mild conditions, various well-defined polymers with complex architecture, such as block and graft copolymers, sequence-controlled polymers, or hybrid materials via surface-initiated polymerization. It also provides opportunity to manipulate the reaction through spatiotemporal control. This review presents a comprehensive account of the fundamentals and applications of various photomediated CRP techniques, including atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT), nitroxide mediated polymerization (NMP) and other procedures. In addition, mechanistic aspects of other photomediated methods are discussed.

Original language	English
Pages (from-to)	73-125
Number of pages	53
Journal	Progress in Polymer Science
Volume	62
DOIs	https://doi.org/10.1016/j.progpolymsci.2016.06.005
Publication status	Published - 1 Nov 2016
Externally published	Yes

Keywords

ATRP
NMP
Photopolymerization
Radical polymerization
RAFT

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10.1016/j.progpolymsci.2016.06.005

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title = "Photomediated controlled radical polymerization",

abstract = "Photomediated controlled radical polymerization is a versatile method to prepare, under mild conditions, various well-defined polymers with complex architecture, such as block and graft copolymers, sequence-controlled polymers, or hybrid materials via surface-initiated polymerization. It also provides opportunity to manipulate the reaction through spatiotemporal control. This review presents a comprehensive account of the fundamentals and applications of various photomediated CRP techniques, including atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT), nitroxide mediated polymerization (NMP) and other procedures. In addition, mechanistic aspects of other photomediated methods are discussed.",

keywords = "ATRP, NMP, Photopolymerization, Radical polymerization, RAFT",

author = "Xiangcheng Pan and Tasdelen, {Mehmet Atilla} and Joachim Laun and Thomas Junkers and Yusuf Yagci and Krzysztof Matyjaszewski",

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T1 - Photomediated controlled radical polymerization

AU - Pan, Xiangcheng

AU - Tasdelen, Mehmet Atilla

AU - Laun, Joachim

AU - Junkers, Thomas

AU - Yagci, Yusuf

AU - Matyjaszewski, Krzysztof

PY - 2016/11/1

Y1 - 2016/11/1

N2 - Photomediated controlled radical polymerization is a versatile method to prepare, under mild conditions, various well-defined polymers with complex architecture, such as block and graft copolymers, sequence-controlled polymers, or hybrid materials via surface-initiated polymerization. It also provides opportunity to manipulate the reaction through spatiotemporal control. This review presents a comprehensive account of the fundamentals and applications of various photomediated CRP techniques, including atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT), nitroxide mediated polymerization (NMP) and other procedures. In addition, mechanistic aspects of other photomediated methods are discussed.

AB - Photomediated controlled radical polymerization is a versatile method to prepare, under mild conditions, various well-defined polymers with complex architecture, such as block and graft copolymers, sequence-controlled polymers, or hybrid materials via surface-initiated polymerization. It also provides opportunity to manipulate the reaction through spatiotemporal control. This review presents a comprehensive account of the fundamentals and applications of various photomediated CRP techniques, including atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT), nitroxide mediated polymerization (NMP) and other procedures. In addition, mechanistic aspects of other photomediated methods are discussed.

KW - ATRP

KW - NMP

KW - Photopolymerization

KW - Radical polymerization

KW - RAFT

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DO - 10.1016/j.progpolymsci.2016.06.005

M3 - Review Article

AN - SCOPUS:85000839094

SN - 0079-6700

VL - 62

SP - 73

EP - 125

JO - Progress in Polymer Science

JF - Progress in Polymer Science

ER -

Photomediated controlled radical polymerization

Abstract

Keywords

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