Photochemistry of transition metal germylenes and metallacycles

K. E. Litz; J. E. Bender; R. D. Sweeder; M. M. Banaszak Holl; J. W. Kampf

doi:10.1021/om9910367

Photochemistry of transition metal germylenes and metallacycles

K. E. Litz, J. E. Bender, R. D. Sweeder, M. M. Banaszak Holl, J. W. Kampf

Research output: Contribution to journal › Article › Research › peer-review

21 Citations (Scopus)

Abstract

Group 10 metal germylene complexes of general formula (R₃P)₂MGeQ₂ are found to be highly photosensitive. Ambient fluoresent lighting causes complete decomposition of nickel germylene species in less than one minute in the presence of germylene traps. The formation of metallacycle (Et₃P)₂Pt(μ-η²-H ₂CO)Ge[N-(SiMe₃)₂]₂ and the photochemical cycloreversion reaction are also reported.

Original language	English
Pages (from-to)	1186-1189
Number of pages	4
Journal	Organometallics
Volume	19
Issue number	6
DOIs	https://doi.org/10.1021/om9910367
Publication status	Published - 20 Mar 2000
Externally published	Yes

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10.1021/om9910367

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Cite this

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title = "Photochemistry of transition metal germylenes and metallacycles",

abstract = "Group 10 metal germylene complexes of general formula (R3P)2MGeQ2 are found to be highly photosensitive. Ambient fluoresent lighting causes complete decomposition of nickel germylene species in less than one minute in the presence of germylene traps. The formation of metallacycle (Et3P)2Pt(μ-η2-H 2CO)Ge[N-(SiMe3)2]2 and the photochemical cycloreversion reaction are also reported.",

author = "Litz, {K. E.} and Bender, {J. E.} and Sweeder, {R. D.} and {Banaszak Holl}, {M. M.} and Kampf, {J. W.}",

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AU - Bender, J. E.

AU - Sweeder, R. D.

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AU - Kampf, J. W.

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Y1 - 2000/3/20

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AB - Group 10 metal germylene complexes of general formula (R3P)2MGeQ2 are found to be highly photosensitive. Ambient fluoresent lighting causes complete decomposition of nickel germylene species in less than one minute in the presence of germylene traps. The formation of metallacycle (Et3P)2Pt(μ-η2-H 2CO)Ge[N-(SiMe3)2]2 and the photochemical cycloreversion reaction are also reported.

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