Phosphonium plastic crystal salt alloyed with a sodium salt as a solid-state electrolyte for sodium devices: phase behaviour and electrochemical performance

Faezeh Makhlooghiazad, Patrick C Howlett, Xiaoen Wang, Matthias Hilder, Douglas R Macfarlane, Michel Armand, Maria Forsyth

Research output: Contribution to journalArticleResearchpeer-review

37 Citations (Scopus)


Mixtures of triisobutylmethylphosphonium bis(fluorosulfonyl)imide (P1i444FSI) with different concentrations of NaFSI display composition-dependent phase behaviour with depression of the melting point upon NaFSI addition and suppression of crystallisation in the middle of the phase diagram and a higher-melting-point, NaFSI-rich mixed-phase region at compositions beyond 60 mol% NaFSI. Thermal treatment of the intermediate compositions results in complete crystallisation of the materials. All compositions showed high ionic conductivity (>10-5 S cm-1) at 20 °C, and Na symmetric cells containing high concentration of NaFSI (Na|[Na0.9(P1i444)0.1]FSI|Na) were cycled efficiently at 50 and 90 °C at 0.05 and 0.1 mA cm-2, respectively. Intermediate composition (Na|[Na0.6(P1i444)0.4]FSI|Na) cells were cycled at room temperature and 50 °C at 0.25 mA cm-2 with very low and stable cell polarisation (200 mV).

Original languageEnglish
Pages (from-to)5770-5780
Number of pages11
JournalJournal of Materials Chemistry A
Issue number12
Publication statusPublished - 2017

Cite this