Phosphomolybdate-doped-poly(3,4-ethylenedioxythiophene) coated gold nanoparticles: Synthesis, characterization and electrocatalytic reduction of bromate

Syeda Hassan; Yuping Liu; Siraj Sirajuddin; Amber Solangi; Alan Maxwell Bond; Jie Zhang

doi:10.1016/j.aca.2013.04.036

Phosphomolybdate-doped-poly(3,4-ethylenedioxythiophene) coated gold nanoparticles: Synthesis, characterization and electrocatalytic reduction of bromate

Syeda Hassan, Yuping Liu, Siraj Sirajuddin, Amber Solangi, Alan Maxwell Bond, Jie Zhang

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

32 Citations (Scopus)

Abstract

Phosphomolybdate, H₃PMo₁₂O₄₀, (PMo₁₂)-doped-poly(3,4-ethylenedioxythiophene) (PEDOT) coated gold nanoparticles have been synthesized in aqueous solution by reduction of AuCl₄⁻ using hydroxymethyl EDOT as a reducing agent in the presence of polystyrene sulfonate and PMo₁₂. The resulting PMo₁₂-doped-PEDOT stabilized Au nanoparticles are water soluble and have been characterized by UV–visible spectroscopy, scanning electron microscopy and electrochemistry. Glassy carbon electrodes modified with these Au nanoparticles show excellent stability and catalytic activity towards the reduction of bromate in an aqueous electrolyte solution containing 10 mM H₂SO₄ and 0.1 M Na₂SO₄.

Original language	English
Pages (from-to)	41 - 46
Number of pages	6
Journal	Analytica Chimica Acta
Volume	803
DOIs	https://doi.org/10.1016/j.aca.2013.04.036
Publication status	Published - 2013

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@article{53d299ff03f843d681fe226fdc7ecd70,

title = "Phosphomolybdate-doped-poly(3,4-ethylenedioxythiophene) coated gold nanoparticles: Synthesis, characterization and electrocatalytic reduction of bromate",

abstract = "Phosphomolybdate, H3PMo12O40, (PMo12)-doped-poly(3,4-ethylenedioxythiophene) (PEDOT) coated gold nanoparticles have been synthesized in aqueous solution by reduction of AuCl4− using hydroxymethyl EDOT as a reducing agent in the presence of polystyrene sulfonate and PMo12. The resulting PMo12-doped-PEDOT stabilized Au nanoparticles are water soluble and have been characterized by UV–visible spectroscopy, scanning electron microscopy and electrochemistry. Glassy carbon electrodes modified with these Au nanoparticles show excellent stability and catalytic activity towards the reduction of bromate in an aqueous electrolyte solution containing 10 mM H2SO4 and 0.1 M Na2SO4.",

author = "Syeda Hassan and Yuping Liu and Siraj Sirajuddin and Amber Solangi and Bond, {Alan Maxwell} and Jie Zhang",

year = "2013",

doi = "10.1016/j.aca.2013.04.036",

language = "English",

volume = "803",

pages = "41 -- 46",

journal = "Analytica Chimica Acta",

issn = "0003-2670",

publisher = "Elsevier BV",

}

TY - JOUR

T1 - Phosphomolybdate-doped-poly(3,4-ethylenedioxythiophene) coated gold nanoparticles

T2 - Synthesis, characterization and electrocatalytic reduction of bromate

AU - Hassan, Syeda

AU - Liu, Yuping

AU - Sirajuddin, Siraj

AU - Solangi, Amber

AU - Bond, Alan Maxwell

AU - Zhang, Jie

PY - 2013

Y1 - 2013

N2 - Phosphomolybdate, H3PMo12O40, (PMo12)-doped-poly(3,4-ethylenedioxythiophene) (PEDOT) coated gold nanoparticles have been synthesized in aqueous solution by reduction of AuCl4− using hydroxymethyl EDOT as a reducing agent in the presence of polystyrene sulfonate and PMo12. The resulting PMo12-doped-PEDOT stabilized Au nanoparticles are water soluble and have been characterized by UV–visible spectroscopy, scanning electron microscopy and electrochemistry. Glassy carbon electrodes modified with these Au nanoparticles show excellent stability and catalytic activity towards the reduction of bromate in an aqueous electrolyte solution containing 10 mM H2SO4 and 0.1 M Na2SO4.

AB - Phosphomolybdate, H3PMo12O40, (PMo12)-doped-poly(3,4-ethylenedioxythiophene) (PEDOT) coated gold nanoparticles have been synthesized in aqueous solution by reduction of AuCl4− using hydroxymethyl EDOT as a reducing agent in the presence of polystyrene sulfonate and PMo12. The resulting PMo12-doped-PEDOT stabilized Au nanoparticles are water soluble and have been characterized by UV–visible spectroscopy, scanning electron microscopy and electrochemistry. Glassy carbon electrodes modified with these Au nanoparticles show excellent stability and catalytic activity towards the reduction of bromate in an aqueous electrolyte solution containing 10 mM H2SO4 and 0.1 M Na2SO4.

U2 - 10.1016/j.aca.2013.04.036

DO - 10.1016/j.aca.2013.04.036

M3 - Article

SN - 0003-2670

VL - 803

SP - 41

EP - 46

JO - Analytica Chimica Acta

JF - Analytica Chimica Acta

ER -

Phosphomolybdate-doped-poly(3,4-ethylenedioxythiophene) coated gold nanoparticles: Synthesis, characterization and electrocatalytic reduction of bromate

Abstract

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