Phospha-alkyne hydro-osmiation: Synthesis of [Os{κ1P,κ1P'-P=CRP(=CHR)}Cl(CO)(PPh3)2] (R = CMe3)

Anthony F. Hill, Cameron Jones, James D.E.T. Wilton-Ely

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12 Citations (Scopus)

Abstract

The reaction of [OsHCl(CO)(PPh3)2(BTD)] (BTD = 2,1,3-benzothiadiazole) with P≡CCMe3 provides the novel complex [Os(κ1P,κ1P'-P=CRP(=CHR)Cl(CO)(PPh3)2] (R = CMe3) which features both phospha-alkenyl and phospha-alkene donors within the same metallacycle.

Original languageEnglish
Pages (from-to)451-452
Number of pages2
JournalChemical Communications
Issue number5
DOIs
Publication statusPublished - 7 Mar 1999
Externally publishedYes

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