Palladium-mediated transfer of oxygen from carbonate ion to an organic ligand

Patricia S. Elmes; Gary D. Fallon; Bryan M K C Gatehouse; W. Roy Jackson; Anna Stragalinou; Bruce O. West

doi:10.1039/C39810000661

Palladium-mediated transfer of oxygen from carbonate ion to an organic ligand

Patricia S. Elmes, Gary D. Fallon, Bryan M K C Gatehouse, W. Roy Jackson, Anna Stragalinou, Bruce O. West

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

2 Citations (Scopus)

Abstract

Reaction of some αβ-unsaturated ketones with palladium(II) chloride and sodium carbonate in tetrahydrofuran (THF) gives acetylacetonate complexes; use of ¹⁸O-enriched carbonate shows that the reaction involves a highly unusual transfer of oxygen from carbonate ion to the organic ligand.

Original language	English
Pages (from-to)	661-662
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	14
DOIs	https://doi.org/10.1039/C39810000661
Publication status	Published - 1 Jan 1981

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10.1039/C39810000661

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Cite this

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title = "Palladium-mediated transfer of oxygen from carbonate ion to an organic ligand",

abstract = "Reaction of some αβ-unsaturated ketones with palladium(II) chloride and sodium carbonate in tetrahydrofuran (THF) gives acetylacetonate complexes; use of 18O-enriched carbonate shows that the reaction involves a highly unusual transfer of oxygen from carbonate ion to the organic ligand.",

author = "Elmes, {Patricia S.} and Fallon, {Gary D.} and Gatehouse, {Bryan M K C} and Jackson, {W. Roy} and Anna Stragalinou and West, {Bruce O.}",

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journal = "Journal of the Chemical Society, Chemical Communications",

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AU - Elmes, Patricia S.

AU - Fallon, Gary D.

AU - Gatehouse, Bryan M K C

AU - Jackson, W. Roy

AU - Stragalinou, Anna

AU - West, Bruce O.

PY - 1981/1/1

Y1 - 1981/1/1

N2 - Reaction of some αβ-unsaturated ketones with palladium(II) chloride and sodium carbonate in tetrahydrofuran (THF) gives acetylacetonate complexes; use of 18O-enriched carbonate shows that the reaction involves a highly unusual transfer of oxygen from carbonate ion to the organic ligand.

AB - Reaction of some αβ-unsaturated ketones with palladium(II) chloride and sodium carbonate in tetrahydrofuran (THF) gives acetylacetonate complexes; use of 18O-enriched carbonate shows that the reaction involves a highly unusual transfer of oxygen from carbonate ion to the organic ligand.

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JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

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