Oxygenation of styrenes catalyzed by N-doped carbon incarcerated cobalt nanoparticles

Tomohiro Yasukawa; Shū Kobayashi

doi:10.1246/bcsj.20190251

Oxygenation of styrenes catalyzed by N-doped carbon incarcerated cobalt nanoparticles

Tomohiro Yasukawa, Shū Kobayashi

Research output: Contribution to journal › Article › Research › peer-review

14 Citations (Scopus)

Abstract

We found that cobalt nanoparticle catalysts supported on nitrogen-doped carbon could facilitate oxygenation of styrenes in a heterogeneous manner. Both the nitrogen dopant and cobalt species were essential to promote the reactions. Based on several mechanistic studies, the formation of radical intermediates on cobalt nanoparticles is proposed.

Original language	English
Pages (from-to)	1980-1985
Number of pages	6
Journal	Bulletin of the Chemical Society of Japan
Volume	92
Issue number	12
DOIs	https://doi.org/10.1246/bcsj.20190251
Publication status	Published - 2019
Externally published	Yes

Keywords

Cobalt nanoparticles
Nitrogen-doped carbon
Olefin oxygenation

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10.1246/bcsj.20190251

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title = "Oxygenation of styrenes catalyzed by N-doped carbon incarcerated cobalt nanoparticles",

abstract = "We found that cobalt nanoparticle catalysts supported on nitrogen-doped carbon could facilitate oxygenation of styrenes in a heterogeneous manner. Both the nitrogen dopant and cobalt species were essential to promote the reactions. Based on several mechanistic studies, the formation of radical intermediates on cobalt nanoparticles is proposed.",

keywords = "Cobalt nanoparticles, Nitrogen-doped carbon, Olefin oxygenation",

author = "Tomohiro Yasukawa and Shū Kobayashi",

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language = "English",

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T1 - Oxygenation of styrenes catalyzed by N-doped carbon incarcerated cobalt nanoparticles

AU - Yasukawa, Tomohiro

AU - Kobayashi, Shū

PY - 2019

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AB - We found that cobalt nanoparticle catalysts supported on nitrogen-doped carbon could facilitate oxygenation of styrenes in a heterogeneous manner. Both the nitrogen dopant and cobalt species were essential to promote the reactions. Based on several mechanistic studies, the formation of radical intermediates on cobalt nanoparticles is proposed.

KW - Cobalt nanoparticles

KW - Nitrogen-doped carbon

KW - Olefin oxygenation

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U2 - 10.1246/bcsj.20190251

DO - 10.1246/bcsj.20190251

M3 - Article

AN - SCOPUS:85076535256

SN - 0009-2673

VL - 92

SP - 1980

EP - 1985

JO - Bulletin of the Chemical Society of Japan

JF - Bulletin of the Chemical Society of Japan

IS - 12

ER -

Oxygenation of styrenes catalyzed by N-doped carbon incarcerated cobalt nanoparticles

Abstract

Keywords

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