Oxidative Cross-Coupling of Boron and Antimony Nucleophiles via Palladium(I)

Quillon Simpson; Matthew J.G. Sinclair; David W. Lupton; Adrian B. Chaplin; Joel F. Hooper

doi:10.1021/acs.orglett.8b01989

Oxidative Cross-Coupling of Boron and Antimony Nucleophiles via Palladium(I)

Quillon Simpson, Matthew J.G. Sinclair, David W. Lupton, Adrian B. Chaplin, Joel F. Hooper

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

6 Citations (Scopus)

Abstract

The use of an isolatable, monomeric Pd(I) complex as a catalyst for the oxidative cross-coupling of aryl-antimony and aryl-boron nucleophiles is reported. This reaction tolerates a wide variety of substrates, with >20:1 selectivity for cross-coupled products. This strategy offers a new approach to achieving the selective cross-coupling of nucleophiles.

Original language	English
Pages (from-to)	5537-5540
Number of pages	4
Journal	Organic Letters
Volume	20
Issue number	18
DOIs	https://doi.org/10.1021/acs.orglett.8b01989
Publication status	Published - 21 Sep 2018

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Cite this

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title = "Oxidative Cross-Coupling of Boron and Antimony Nucleophiles via Palladium(I)",

abstract = "The use of an isolatable, monomeric Pd(I) complex as a catalyst for the oxidative cross-coupling of aryl-antimony and aryl-boron nucleophiles is reported. This reaction tolerates a wide variety of substrates, with >20:1 selectivity for cross-coupled products. This strategy offers a new approach to achieving the selective cross-coupling of nucleophiles.",

author = "Quillon Simpson and Sinclair, {Matthew J.G.} and Lupton, {David W.} and Chaplin, {Adrian B.} and Hooper, {Joel F.}",

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AU - Simpson, Quillon

AU - Sinclair, Matthew J.G.

AU - Lupton, David W.

AU - Chaplin, Adrian B.

AU - Hooper, Joel F.

PY - 2018/9/21

Y1 - 2018/9/21

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AB - The use of an isolatable, monomeric Pd(I) complex as a catalyst for the oxidative cross-coupling of aryl-antimony and aryl-boron nucleophiles is reported. This reaction tolerates a wide variety of substrates, with >20:1 selectivity for cross-coupled products. This strategy offers a new approach to achieving the selective cross-coupling of nucleophiles.

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JO - Organic Letters

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