Oxidative addition of water and methanol to a dicationic trivalent phosphorus centre

Madelyn Qin Yi Tay; Yunpeng Lu; Rakesh Ganguly; Dragoslav Vidovic̈

doi:10.1002/chem.201402356

Oxidative addition of water and methanol to a dicationic trivalent phosphorus centre

Madelyn Qin Yi Tay, Yunpeng Lu, Rakesh Ganguly, Dragoslav Vidovic̈

Research output: Contribution to journal › Article › Research › peer-review

25 Citations (Scopus)

Abstract

Our recently synthesised phosphorus dication is observed to activate water (and methanol) under reactions conditions atypical for other systems containing a non-metal centre. This particular activation described as oxidative addition is quite rare and has been reserved exclusively for a couple of metal-based compounds.

Original language	English
Pages (from-to)	6628-6631
Number of pages	4
Journal	Chemistry - A European Journal
Volume	20
Issue number	22
DOIs	https://doi.org/10.1002/chem.201402356
Publication status	Published - 26 May 2014
Externally published	Yes

Keywords

dications
NMR spectroscopy
oxidative addition
phosphorus
water activation

Access to Document

10.1002/chem.201402356

Cite this

@article{53626552024f4733b2d5b7c9c114a62d,

title = "Oxidative addition of water and methanol to a dicationic trivalent phosphorus centre",

abstract = "Our recently synthesised phosphorus dication is observed to activate water (and methanol) under reactions conditions atypical for other systems containing a non-metal centre. This particular activation described as oxidative addition is quite rare and has been reserved exclusively for a couple of metal-based compounds.",

keywords = "dications, NMR spectroscopy, oxidative addition, phosphorus, water activation",

author = "Tay, \{Madelyn Qin Yi\} and Yunpeng Lu and Rakesh Ganguly and Dragoslav Vidovi{\"c}",

year = "2014",

month = may,

day = "26",

doi = "10.1002/chem.201402356",

language = "English",

volume = "20",

pages = "6628--6631",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "Wiley-VCH Verlag GmbH \& Co. KGaA",

number = "22",

}

TY - JOUR

T1 - Oxidative addition of water and methanol to a dicationic trivalent phosphorus centre

AU - Tay, Madelyn Qin Yi

AU - Lu, Yunpeng

AU - Ganguly, Rakesh

AU - Vidovic̈, Dragoslav

PY - 2014/5/26

Y1 - 2014/5/26

N2 - Our recently synthesised phosphorus dication is observed to activate water (and methanol) under reactions conditions atypical for other systems containing a non-metal centre. This particular activation described as oxidative addition is quite rare and has been reserved exclusively for a couple of metal-based compounds.

AB - Our recently synthesised phosphorus dication is observed to activate water (and methanol) under reactions conditions atypical for other systems containing a non-metal centre. This particular activation described as oxidative addition is quite rare and has been reserved exclusively for a couple of metal-based compounds.

KW - dications

KW - NMR spectroscopy

KW - oxidative addition

KW - phosphorus

KW - water activation

UR - https://www.scopus.com/pages/publications/84901316099

U2 - 10.1002/chem.201402356

DO - 10.1002/chem.201402356

M3 - Article

AN - SCOPUS:84901316099

SN - 0947-6539

VL - 20

SP - 6628

EP - 6631

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 22

ER -

Oxidative addition of water and methanol to a dicationic trivalent phosphorus centre

Abstract

Keywords

Access to Document

Other files and links

Cite this