Oxazolidinone-promoted, torquoselective Nazarov cyclizations

Daniel Jarrah Kerr, Michael Miletic, Jason H Chaplin, Jonathan Michael White, Bernard Luke Flynn

Research output: Contribution to journalArticleResearchpeer-review

49 Citations (Scopus)

Abstract

Oxazolidinones are powerful promoters of the Nazarov reaction, enabling the cyclization of conventionally resistant substrates to be achieved under mild conditions. They exert excellent regio- and torquoselective control in both the conventional Nazarov reaction giving cyclopentenones and in the interrupted Nazarov reaction, giving more highly substituted multistereocenter containing products.
Original languageEnglish
Pages (from-to)1732 - 1735
Number of pages4
JournalOrganic Letters
Volume14
Issue number7
DOIs
Publication statusPublished - 2012

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