Oxazolidinone-promoted, torquoselective Nazarov cyclizations

Daniel Jarrah Kerr, Michael Miletic, Jason H Chaplin, Jonathan Michael White, Bernard Luke Flynn

Research output: Contribution to journalArticleResearchpeer-review

46 Citations (Scopus)

Abstract

Oxazolidinones are powerful promoters of the Nazarov reaction, enabling the cyclization of conventionally resistant substrates to be achieved under mild conditions. They exert excellent regio- and torquoselective control in both the conventional Nazarov reaction giving cyclopentenones and in the interrupted Nazarov reaction, giving more highly substituted multistereocenter containing products.
Original languageEnglish
Pages (from-to)1732 - 1735
Number of pages4
JournalOrganic Letters
Volume14
Issue number7
DOIs
Publication statusPublished - 2012

Cite this

Kerr, D. J., Miletic, M., Chaplin, J. H., White, J. M., & Flynn, B. L. (2012). Oxazolidinone-promoted, torquoselective Nazarov cyclizations. Organic Letters, 14(7), 1732 - 1735. https://doi.org/10.1021/ol300316a
Kerr, Daniel Jarrah ; Miletic, Michael ; Chaplin, Jason H ; White, Jonathan Michael ; Flynn, Bernard Luke. / Oxazolidinone-promoted, torquoselective Nazarov cyclizations. In: Organic Letters. 2012 ; Vol. 14, No. 7. pp. 1732 - 1735.
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Kerr, DJ, Miletic, M, Chaplin, JH, White, JM & Flynn, BL 2012, 'Oxazolidinone-promoted, torquoselective Nazarov cyclizations', Organic Letters, vol. 14, no. 7, pp. 1732 - 1735. https://doi.org/10.1021/ol300316a

Oxazolidinone-promoted, torquoselective Nazarov cyclizations. / Kerr, Daniel Jarrah; Miletic, Michael; Chaplin, Jason H; White, Jonathan Michael; Flynn, Bernard Luke.

In: Organic Letters, Vol. 14, No. 7, 2012, p. 1732 - 1735.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Oxazolidinone-promoted, torquoselective Nazarov cyclizations

AU - Kerr, Daniel Jarrah

AU - Miletic, Michael

AU - Chaplin, Jason H

AU - White, Jonathan Michael

AU - Flynn, Bernard Luke

PY - 2012

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AB - Oxazolidinones are powerful promoters of the Nazarov reaction, enabling the cyclization of conventionally resistant substrates to be achieved under mild conditions. They exert excellent regio- and torquoselective control in both the conventional Nazarov reaction giving cyclopentenones and in the interrupted Nazarov reaction, giving more highly substituted multistereocenter containing products.

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U2 - 10.1021/ol300316a

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JF - Organic Letters

SN - 1523-7060

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