TY - JOUR
T1 - Osmotic power generation with positively and negatively charged 2D nanofluidic membrane pairs
AU - Ji, Jinzhao
AU - Kang, Qian
AU - Zhou, Yi
AU - Feng, Yaping
AU - Chen, Xi
AU - Yuan, Jinying
AU - Guo, Wei
AU - Wei, Yen
AU - Jiang, Lei
PY - 2017/1/12
Y1 - 2017/1/12
N2 - In nature, hierarchically assembled nanoscale ionic conductors, such as ion channels and ion pumps, become the structural and functional basis of bioelectric phenomena. Recently, ion-channel-mimetic nanofluidic systems have been built into reconstructed 2D nanomaterials for energy conversion and storage as effective as the electrogenic cells. Here, a 2D-material-based nanofluidic reverse electrodialysis system, containing cascading lamellar nanochannels in oppositely charged graphene oxide membrane (GOM) pairs, is reported for efficient osmotic energy conversion. Through preassembly modification, the surface charge polarity of the 2D nanochannels can be efficiently tuned from negative (−123 mC m−2) to positive (+147 mC m−2), yielding strongly cation- or anion-selective GOMs. The complementary two-way ion diffusion leads to an efficient charge separation process, creating superposed electrochemical potential difference and ionic flux. An output power density of 0.77 W m−2 is achieved by controlled mixing concentrated (0.5 m) and diluted ionic solutions (0.01 m), which is about 54% higher than using commercial ion exchange membranes. Tandem alternating GOM pairs produce high voltage up to 2.7 V to power electronic devices. Besides simple salt solutions, various complex electrolyte solutions can be used as energy sources. These findings provide insights to construct cascading nanofluidic circuits for energy, environmental, and healthcare applications.
AB - In nature, hierarchically assembled nanoscale ionic conductors, such as ion channels and ion pumps, become the structural and functional basis of bioelectric phenomena. Recently, ion-channel-mimetic nanofluidic systems have been built into reconstructed 2D nanomaterials for energy conversion and storage as effective as the electrogenic cells. Here, a 2D-material-based nanofluidic reverse electrodialysis system, containing cascading lamellar nanochannels in oppositely charged graphene oxide membrane (GOM) pairs, is reported for efficient osmotic energy conversion. Through preassembly modification, the surface charge polarity of the 2D nanochannels can be efficiently tuned from negative (−123 mC m−2) to positive (+147 mC m−2), yielding strongly cation- or anion-selective GOMs. The complementary two-way ion diffusion leads to an efficient charge separation process, creating superposed electrochemical potential difference and ionic flux. An output power density of 0.77 W m−2 is achieved by controlled mixing concentrated (0.5 m) and diluted ionic solutions (0.01 m), which is about 54% higher than using commercial ion exchange membranes. Tandem alternating GOM pairs produce high voltage up to 2.7 V to power electronic devices. Besides simple salt solutions, various complex electrolyte solutions can be used as energy sources. These findings provide insights to construct cascading nanofluidic circuits for energy, environmental, and healthcare applications.
KW - 2D materials
KW - biomimetics
KW - energy conversion
KW - ion transport
KW - nanofluidics
UR - http://www.scopus.com/inward/record.url?scp=84995543215&partnerID=8YFLogxK
U2 - 10.1002/adfm.201603623
DO - 10.1002/adfm.201603623
M3 - Article
AN - SCOPUS:84995543215
VL - 27
JO - Advanced Functional Materials
JF - Advanced Functional Materials
SN - 1616-301X
IS - 2
M1 - 1603623
ER -