Organothallium compounds. VI. Reactions of bromobis(pentafluorophenyl)thallium(III) with main group elements

G. B. Deacon, J. C. Parrott

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Abstract

Bromobis(pentafluorophenyl)thallium(IlI) reacts with many main group elements on heating in the absence of a solvent to give pentafluorophenyl derivatsves of these elements. The compounds C6F5M (M = Cl, Br, or I), (C6F5)2M (M = Zn, Cd, Hg, S, Se or Te), (C6F5)3M (M = In, P, As, or Sb), and (C6F5)M (M = Ge or Sn) have been prepared by this method. Substantial decomposition of (C6F5)2TlBr occurs on reaction with aluminium, gallium, lead and bismuth, but pcntafluorophenyl derivatives of these élements are not obtained.

Original languageEnglish
Pages (from-to)287-295
Number of pages9
JournalJournal of Organometallic Chemistry
Volume22
Issue number2
DOIs
Publication statusPublished - 1 Jan 1970

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