Organometallic catalysis for applications in radical chemistry and asymmetric synthesis

Corinne Aubert; Marion Barbazanges; Anny Jutand; Sara H. Kyne; Cyril Ollivier; Louis Fensterbank

doi:10.1515/pac-2014-5030

Organometallic catalysis for applications in radical chemistry and asymmetric synthesis

Corinne Aubert, Marion Barbazanges, Anny Jutand, Sara H. Kyne, Cyril Ollivier, Louis Fensterbank

Research output: Contribution to journal › Article › Research › peer-review

Abstract

Two organometallic catalysis studies are presented. The first one deals with the development of a new catalytic agent based on the mixture of a hydride and an iron salt to trigger efficient radical cyclization processes. In a second line of research, we have shown that the use of chiral anions can outperform chiral ligands in a carbocyclization reaction and a [2 + 2 + 2] cycloaddition.

Original language	English
Pages (from-to)	273-281
Number of pages	9
Journal	Pure and Applied Chemistry
Volume	86
Issue number	3
DOIs	https://doi.org/10.1515/pac-2014-5030
Publication status	Published - 20 Mar 2014
Externally published	Yes

Keywords

carbocyclizations
chirality
electrochemistry
homogeneous catalysis
hydrides
ion pairs
iron
OMCOS-17
radicals

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T1 - Organometallic catalysis for applications in radical chemistry and asymmetric synthesis

AU - Aubert, Corinne

AU - Barbazanges, Marion

AU - Jutand, Anny

AU - Kyne, Sara H.

AU - Ollivier, Cyril

AU - Fensterbank, Louis

PY - 2014/3/20

Y1 - 2014/3/20

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AB - Two organometallic catalysis studies are presented. The first one deals with the development of a new catalytic agent based on the mixture of a hydride and an iron salt to trigger efficient radical cyclization processes. In a second line of research, we have shown that the use of chiral anions can outperform chiral ligands in a carbocyclization reaction and a [2 + 2 + 2] cycloaddition.

KW - carbocyclizations

KW - chirality

KW - electrochemistry

KW - homogeneous catalysis

KW - hydrides

KW - ion pairs

KW - iron

KW - OMCOS-17

KW - radicals

UR - http://www.scopus.com/inward/record.url?scp=84896304157&partnerID=8YFLogxK

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DO - 10.1515/pac-2014-5030

M3 - Article

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VL - 86

SP - 273

EP - 281

JO - Pure and Applied Chemistry

JF - Pure and Applied Chemistry

IS - 3

ER -

Organometallic catalysis for applications in radical chemistry and asymmetric synthesis

Abstract

Keywords

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