Organomercury Derivatives of Dibenzoylmethane

R. J. Bertino, G. B. Deacon

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Abstract

From reaction of dibenzoylmethane or its monosodium salt with suitable monoorganomercurials or mercuric acetate, the dimercurated complexes XHgC(COPh)2HgX (X = C6F5,p-HC6F4, Ph, or MeCO2) and the adducts HC(COPh) (COHPh) ·2C6F5HgY (Y = Cl or Br) have been prepared. In the complexes, dibenzoylmethane is chelated through oxygen to one mercury atom and is carbon-bonded to other, whilst in the adducts the enolic form of dibenzoylmethane is possibly weakly coordinated to two mercury atoms.

Original languageEnglish
JournalJournal of Organometallic Chemistry
Volume67
Issue number3
DOIs
Publication statusPublished - 19 Mar 1974

Cite this

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title = "Organomercury Derivatives of Dibenzoylmethane",
abstract = "From reaction of dibenzoylmethane or its monosodium salt with suitable monoorganomercurials or mercuric acetate, the dimercurated complexes XHgC(COPh)2HgX (X = C6F5,p-HC6F4, Ph, or MeCO2) and the adducts HC(COPh) (COHPh) ·2C6F5HgY (Y = Cl or Br) have been prepared. In the complexes, dibenzoylmethane is chelated through oxygen to one mercury atom and is carbon-bonded to other, whilst in the adducts the enolic form of dibenzoylmethane is possibly weakly coordinated to two mercury atoms.",
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Organomercury Derivatives of Dibenzoylmethane. / Bertino, R. J.; Deacon, G. B.

In: Journal of Organometallic Chemistry, Vol. 67, No. 3, 19.03.1974.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Organomercury Derivatives of Dibenzoylmethane

AU - Bertino, R. J.

AU - Deacon, G. B.

PY - 1974/3/19

Y1 - 1974/3/19

N2 - From reaction of dibenzoylmethane or its monosodium salt with suitable monoorganomercurials or mercuric acetate, the dimercurated complexes XHgC(COPh)2HgX (X = C6F5,p-HC6F4, Ph, or MeCO2) and the adducts HC(COPh) (COHPh) ·2C6F5HgY (Y = Cl or Br) have been prepared. In the complexes, dibenzoylmethane is chelated through oxygen to one mercury atom and is carbon-bonded to other, whilst in the adducts the enolic form of dibenzoylmethane is possibly weakly coordinated to two mercury atoms.

AB - From reaction of dibenzoylmethane or its monosodium salt with suitable monoorganomercurials or mercuric acetate, the dimercurated complexes XHgC(COPh)2HgX (X = C6F5,p-HC6F4, Ph, or MeCO2) and the adducts HC(COPh) (COHPh) ·2C6F5HgY (Y = Cl or Br) have been prepared. In the complexes, dibenzoylmethane is chelated through oxygen to one mercury atom and is carbon-bonded to other, whilst in the adducts the enolic form of dibenzoylmethane is possibly weakly coordinated to two mercury atoms.

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U2 - 10.1016/S0022-328X(00)88170-X

DO - 10.1016/S0022-328X(00)88170-X

M3 - Article

VL - 67

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

IS - 3

ER -