TY - JOUR
T1 - Organomercury compounds:XI. Some coordination derivatives of bispentafluorophenylmercury
AU - Canty, A. J.
AU - Deacon, G. B.
PY - 1971/1/1
Y1 - 1971/1/1
N2 - The complexes (C6F5)2HgL (L = 4, 4'-dimethyl-2, 2'-bipyridyl, 2, 2'- biquinolyl, 2, 2':6', 2"-terpyridyl, 2, 4, 7, 9,-tetramethyl-1, 10- phenanthroline, ethylenediamine, o-phenylenediamine, diphenylamine, pyridine, 4-cyanopyridine, triphenylphosphine, triphenylphosphine oxide, or 1, 2-bisdiphenylarsinoethane), (C6F5)2HgL2 (L = di-2-pyridylamine), and [(C6F5)2Hg]2L (L = bisdiphenylphosphinomethane or bisdiphenyl-arsinomethane) have been prepared, and their constitution, solution stabilities, and structures studied, together with those of the known complexes (C6F5)2HgL (L = 2, 2'-bipyridyl, 1, 10-phenanthroline, or 1, 2-bisdiphenylphosphinoethane). Coordination of triphenylarsine oxide to bispentafluorophenylmercury in solution has also been detected, but the complex could not be isolated.
AB - The complexes (C6F5)2HgL (L = 4, 4'-dimethyl-2, 2'-bipyridyl, 2, 2'- biquinolyl, 2, 2':6', 2"-terpyridyl, 2, 4, 7, 9,-tetramethyl-1, 10- phenanthroline, ethylenediamine, o-phenylenediamine, diphenylamine, pyridine, 4-cyanopyridine, triphenylphosphine, triphenylphosphine oxide, or 1, 2-bisdiphenylarsinoethane), (C6F5)2HgL2 (L = di-2-pyridylamine), and [(C6F5)2Hg]2L (L = bisdiphenylphosphinomethane or bisdiphenyl-arsinomethane) have been prepared, and their constitution, solution stabilities, and structures studied, together with those of the known complexes (C6F5)2HgL (L = 2, 2'-bipyridyl, 1, 10-phenanthroline, or 1, 2-bisdiphenylphosphinoethane). Coordination of triphenylarsine oxide to bispentafluorophenylmercury in solution has also been detected, but the complex could not be isolated.
UR - http://www.scopus.com/inward/record.url?scp=84971055512&partnerID=8YFLogxK
U2 - 10.1071/CH9710489
DO - 10.1071/CH9710489
M3 - Article
AN - SCOPUS:84971055512
VL - 24
SP - 489
EP - 499
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
SN - 0004-9425
IS - 3
ER -