TY - JOUR
T1 - Organomercury compounds. XXX.The synthesis and crystal and molecular structure of bis(2,4,6-trichlorophenoxymethyl) mercury
AU - Deacon, G. B.
AU - Gatehouse, B. M.
AU - Ney, S.C.
PY - 1988/7/5
Y1 - 1988/7/5
N2 - Bis(2,4,6-trichlorophenoxymethyl)mercury has been prepared by reaction of bis(bromomethyl)mercury with thallium(I) 2,4,6-trichlorophenoxide. The compound has a centrosymmetric structure with linear CHgC bonding (HgC 2.11(1) Å). Each mercury has contacts with two intramolecular and two intermolecular oxygen atoms (Hg ... O 2.970(6) and 3.105(6) Å, respectively) and with an ortho-chlorine from each trichlorophenyl ring (Hg Cl 3.419(2) Å). The other ortho-chlorines have contacts with a methylene hydrogen (H ... Cl 2.874(3) Å).
AB - Bis(2,4,6-trichlorophenoxymethyl)mercury has been prepared by reaction of bis(bromomethyl)mercury with thallium(I) 2,4,6-trichlorophenoxide. The compound has a centrosymmetric structure with linear CHgC bonding (HgC 2.11(1) Å). Each mercury has contacts with two intramolecular and two intermolecular oxygen atoms (Hg ... O 2.970(6) and 3.105(6) Å, respectively) and with an ortho-chlorine from each trichlorophenyl ring (Hg Cl 3.419(2) Å). The other ortho-chlorines have contacts with a methylene hydrogen (H ... Cl 2.874(3) Å).
UR - https://www.scopus.com/pages/publications/45449123166
U2 - 10.1016/0022-328X(88)80389-9
DO - 10.1016/0022-328X(88)80389-9
M3 - Article
AN - SCOPUS:45449123166
SN - 0022-328X
VL - 348
SP - 141
EP - 147
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 2
ER -