TY - JOUR
T1 - Organomercury compounds. Part V. Preparations of pentachlorophenylmercury compounds by decarboxylation reactions
AU - Deacon, G. B.
AU - Felder, P. W.
PY - 1967/12/1
Y1 - 1967/12/1
N2 - Mercuric pentachlorobenzoate and arylmercuric pentachlorobenzoates, RHgOCO·C6Cl5 (R=Ph, p-MeC6H4, or p-MeO·C6H4), undergo decarboxylation in boiling pyridine to give bispentachlorophenylmercury and arylpentachlorophenylmercurials, respectively. Reactions of phenylmercuric chloride, p-tolymercuric chloride, and mercuric chloride with thallous pentachlorobenzoate in boiling pyridine yield pentachlorophenylphenylmercury, pentachlorophenyl-p-tolymercury, and pentachlorophenylmercuric chloride, respectively.
AB - Mercuric pentachlorobenzoate and arylmercuric pentachlorobenzoates, RHgOCO·C6Cl5 (R=Ph, p-MeC6H4, or p-MeO·C6H4), undergo decarboxylation in boiling pyridine to give bispentachlorophenylmercury and arylpentachlorophenylmercurials, respectively. Reactions of phenylmercuric chloride, p-tolymercuric chloride, and mercuric chloride with thallous pentachlorobenzoate in boiling pyridine yield pentachlorophenylphenylmercury, pentachlorophenyl-p-tolymercury, and pentachlorophenylmercuric chloride, respectively.
UR - https://www.scopus.com/pages/publications/37049114391
U2 - 10.1039/J39670002313
DO - 10.1039/J39670002313
M3 - Article
AN - SCOPUS:37049114391
SN - 0022-4952
SP - 2313
EP - 2314
JO - Journal of the Chemical Society C: Organic Chemistry
JF - Journal of the Chemical Society C: Organic Chemistry
ER -