Organomercury compounds. Part V. Preparations of pentachlorophenylmercury compounds by decarboxylation reactions

G. B. Deacon, P. W. Felder

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Mercuric pentachlorobenzoate and arylmercuric pentachlorobenzoates, RHgOCO·C6Cl5 (R=Ph, p-MeC6H4, or p-MeO·C6H4), undergo decarboxylation in boiling pyridine to give bispentachlorophenylmercury and arylpentachlorophenylmercurials, respectively. Reactions of phenylmercuric chloride, p-tolymercuric chloride, and mercuric chloride with thallous pentachlorobenzoate in boiling pyridine yield pentachlorophenylphenylmercury, pentachlorophenyl-p-tolymercury, and pentachlorophenylmercuric chloride, respectively.

Original languageEnglish
Pages (from-to)2313-2314
Number of pages2
JournalJournal of the Chemical Society C: Organic Chemistry
DOIs
Publication statusPublished - 1 Dec 1967

Cite this

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title = "Organomercury compounds. Part V. Preparations of pentachlorophenylmercury compounds by decarboxylation reactions",
abstract = "Mercuric pentachlorobenzoate and arylmercuric pentachlorobenzoates, RHgOCO·C6Cl5 (R=Ph, p-MeC6H4, or p-MeO·C6H4), undergo decarboxylation in boiling pyridine to give bispentachlorophenylmercury and arylpentachlorophenylmercurials, respectively. Reactions of phenylmercuric chloride, p-tolymercuric chloride, and mercuric chloride with thallous pentachlorobenzoate in boiling pyridine yield pentachlorophenylphenylmercury, pentachlorophenyl-p-tolymercury, and pentachlorophenylmercuric chloride, respectively.",
author = "Deacon, {G. B.} and Felder, {P. W.}",
year = "1967",
month = "12",
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doi = "10.1039/J39670002313",
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pages = "2313--2314",
journal = "Journal of the Chemical Society C: Organic Chemistry",
issn = "0022-4952",
publisher = "The Royal Society of Chemistry",

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Organomercury compounds. Part V. Preparations of pentachlorophenylmercury compounds by decarboxylation reactions. / Deacon, G. B.; Felder, P. W.

In: Journal of the Chemical Society C: Organic Chemistry, 01.12.1967, p. 2313-2314.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Organomercury compounds. Part V. Preparations of pentachlorophenylmercury compounds by decarboxylation reactions

AU - Deacon, G. B.

AU - Felder, P. W.

PY - 1967/12/1

Y1 - 1967/12/1

N2 - Mercuric pentachlorobenzoate and arylmercuric pentachlorobenzoates, RHgOCO·C6Cl5 (R=Ph, p-MeC6H4, or p-MeO·C6H4), undergo decarboxylation in boiling pyridine to give bispentachlorophenylmercury and arylpentachlorophenylmercurials, respectively. Reactions of phenylmercuric chloride, p-tolymercuric chloride, and mercuric chloride with thallous pentachlorobenzoate in boiling pyridine yield pentachlorophenylphenylmercury, pentachlorophenyl-p-tolymercury, and pentachlorophenylmercuric chloride, respectively.

AB - Mercuric pentachlorobenzoate and arylmercuric pentachlorobenzoates, RHgOCO·C6Cl5 (R=Ph, p-MeC6H4, or p-MeO·C6H4), undergo decarboxylation in boiling pyridine to give bispentachlorophenylmercury and arylpentachlorophenylmercurials, respectively. Reactions of phenylmercuric chloride, p-tolymercuric chloride, and mercuric chloride with thallous pentachlorobenzoate in boiling pyridine yield pentachlorophenylphenylmercury, pentachlorophenyl-p-tolymercury, and pentachlorophenylmercuric chloride, respectively.

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DO - 10.1039/J39670002313

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