Organolanthanoids. XII. Reactions of bis(cyclopentadienyl)ytterbium(II) with some diorganomercurials

G. B. Deacon, D. L. Wilkinson

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Reactions of (C5H5)2Yb(MeOCH2)2 with R2Hg (R = C6F5, C6Cl5, or PhCC) yield mercury metal and (C5H5)2YbR, but diphenylmercury fails to react significantly. Bis(trans-2-chlorovinyl)mercury reacts with (C5H5)2Yb(MeOCH2)2 to give (C5H5)2YbCl. Ligand exchange occurs between (C5H5)2YbC6F5 and phenylacetylene and with succinimide to give (C5H5)2YbCCPh and (C5H5)2YbNC(O)CH2CH2C(O), respectively.

Original languageEnglish
Pages (from-to)155-159
Number of pages5
JournalInorganica Chimica Acta
Volume142
Issue number1
DOIs
Publication statusPublished - 1 Feb 1988

Cite this

@article{c40c6213564f435a86ffb8211b213a4e,
title = "Organolanthanoids. XII. Reactions of bis(cyclopentadienyl)ytterbium(II) with some diorganomercurials",
abstract = "Reactions of (C5H5)2Yb(MeOCH2)2 with R2Hg (R = C6F5, C6Cl5, or PhCC) yield mercury metal and (C5H5)2YbR, but diphenylmercury fails to react significantly. Bis(trans-2-chlorovinyl)mercury reacts with (C5H5)2Yb(MeOCH2)2 to give (C5H5)2YbCl. Ligand exchange occurs between (C5H5)2YbC6F5 and phenylacetylene and with succinimide to give (C5H5)2YbCCPh and (C5H5)2YbNC(O)CH2CH2C(O), respectively.",
author = "Deacon, {G. B.} and Wilkinson, {D. L.}",
year = "1988",
month = "2",
day = "1",
doi = "10.1016/S0020-1693(00)80675-1",
language = "English",
volume = "142",
pages = "155--159",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier",
number = "1",

}

Organolanthanoids. XII. Reactions of bis(cyclopentadienyl)ytterbium(II) with some diorganomercurials. / Deacon, G. B.; Wilkinson, D. L.

In: Inorganica Chimica Acta, Vol. 142, No. 1, 01.02.1988, p. 155-159.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Organolanthanoids. XII. Reactions of bis(cyclopentadienyl)ytterbium(II) with some diorganomercurials

AU - Deacon, G. B.

AU - Wilkinson, D. L.

PY - 1988/2/1

Y1 - 1988/2/1

N2 - Reactions of (C5H5)2Yb(MeOCH2)2 with R2Hg (R = C6F5, C6Cl5, or PhCC) yield mercury metal and (C5H5)2YbR, but diphenylmercury fails to react significantly. Bis(trans-2-chlorovinyl)mercury reacts with (C5H5)2Yb(MeOCH2)2 to give (C5H5)2YbCl. Ligand exchange occurs between (C5H5)2YbC6F5 and phenylacetylene and with succinimide to give (C5H5)2YbCCPh and (C5H5)2YbNC(O)CH2CH2C(O), respectively.

AB - Reactions of (C5H5)2Yb(MeOCH2)2 with R2Hg (R = C6F5, C6Cl5, or PhCC) yield mercury metal and (C5H5)2YbR, but diphenylmercury fails to react significantly. Bis(trans-2-chlorovinyl)mercury reacts with (C5H5)2Yb(MeOCH2)2 to give (C5H5)2YbCl. Ligand exchange occurs between (C5H5)2YbC6F5 and phenylacetylene and with succinimide to give (C5H5)2YbCCPh and (C5H5)2YbNC(O)CH2CH2C(O), respectively.

UR - http://www.scopus.com/inward/record.url?scp=0000983788&partnerID=8YFLogxK

U2 - 10.1016/S0020-1693(00)80675-1

DO - 10.1016/S0020-1693(00)80675-1

M3 - Article

VL - 142

SP - 155

EP - 159

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

IS - 1

ER -