Organolanthanoids. XII. Reactions of bis(cyclopentadienyl)ytterbium(II) with some diorganomercurials

G. B. Deacon; D. L. Wilkinson

doi:10.1016/S0020-1693(00)80675-1

Organolanthanoids. XII. Reactions of bis(cyclopentadienyl)ytterbium(II) with some diorganomercurials

G. B. Deacon, D. L. Wilkinson

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

29 Citations (Scopus)

Abstract

Reactions of (C₅H₅)₂Yb(MeOCH₂)₂ with R₂Hg (R = C₆F₅, C₆Cl₅, or PhCC) yield mercury metal and (C₅H₅)₂YbR, but diphenylmercury fails to react significantly. Bis(trans-2-chlorovinyl)mercury reacts with (C₅H₅)₂Yb(MeOCH₂)₂ to give (C₅H₅)₂YbCl. Ligand exchange occurs between (C₅H₅)₂YbC₆F₅ and phenylacetylene and with succinimide to give (C₅H₅)₂YbCCPh and (C₅H₅)₂YbNC(O)CH₂CH₂C(O), respectively.

Original language	English
Pages (from-to)	155-159
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	142
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(00)80675-1
Publication status	Published - 1 Feb 1988

Access to Document

10.1016/S0020-1693(00)80675-1

Cite this

@article{c40c6213564f435a86ffb8211b213a4e,

title = "Organolanthanoids. XII. Reactions of bis(cyclopentadienyl)ytterbium(II) with some diorganomercurials",

abstract = "Reactions of (C5H5)2Yb(MeOCH2)2 with R2Hg (R = C6F5, C6Cl5, or PhCC) yield mercury metal and (C5H5)2YbR, but diphenylmercury fails to react significantly. Bis(trans-2-chlorovinyl)mercury reacts with (C5H5)2Yb(MeOCH2)2 to give (C5H5)2YbCl. Ligand exchange occurs between (C5H5)2YbC6F5 and phenylacetylene and with succinimide to give (C5H5)2YbCCPh and (C5H5)2YbNC(O)CH2CH2C(O), respectively.",

author = "Deacon, {G. B.} and Wilkinson, {D. L.}",

year = "1988",

month = feb,

day = "1",

doi = "10.1016/S0020-1693(00)80675-1",

language = "English",

volume = "142",

pages = "155--159",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

number = "1",

}

TY - JOUR

T1 - Organolanthanoids. XII. Reactions of bis(cyclopentadienyl)ytterbium(II) with some diorganomercurials

AU - Deacon, G. B.

AU - Wilkinson, D. L.

PY - 1988/2/1

Y1 - 1988/2/1

N2 - Reactions of (C5H5)2Yb(MeOCH2)2 with R2Hg (R = C6F5, C6Cl5, or PhCC) yield mercury metal and (C5H5)2YbR, but diphenylmercury fails to react significantly. Bis(trans-2-chlorovinyl)mercury reacts with (C5H5)2Yb(MeOCH2)2 to give (C5H5)2YbCl. Ligand exchange occurs between (C5H5)2YbC6F5 and phenylacetylene and with succinimide to give (C5H5)2YbCCPh and (C5H5)2YbNC(O)CH2CH2C(O), respectively.

AB - Reactions of (C5H5)2Yb(MeOCH2)2 with R2Hg (R = C6F5, C6Cl5, or PhCC) yield mercury metal and (C5H5)2YbR, but diphenylmercury fails to react significantly. Bis(trans-2-chlorovinyl)mercury reacts with (C5H5)2Yb(MeOCH2)2 to give (C5H5)2YbCl. Ligand exchange occurs between (C5H5)2YbC6F5 and phenylacetylene and with succinimide to give (C5H5)2YbCCPh and (C5H5)2YbNC(O)CH2CH2C(O), respectively.

UR - http://www.scopus.com/inward/record.url?scp=0000983788&partnerID=8YFLogxK

U2 - 10.1016/S0020-1693(00)80675-1

DO - 10.1016/S0020-1693(00)80675-1

M3 - Article

AN - SCOPUS:0000983788

SN - 0020-1693

VL - 142

SP - 155

EP - 159

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1

ER -

Organolanthanoids. XII. Reactions of bis(cyclopentadienyl)ytterbium(II) with some diorganomercurials

Abstract

Access to Document

Other files and links

Cite this