Organolanthanoids. VII. The crystal and molecular structure of dibromo-η5-cyclopentadienyltris(tetrahydrofuran)ytterbium(III)

G. B. Deacon, G. D. Fallon, D. L. Wilkinson

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31 Citations (Scopus)

Abstract

Crystals of dibromo-η5-cyclopentadienyltris(tetrahydrofuran)ytterbium(III) are monoclinic, P21/n (C2n5, No. 14), with a 15.310(15), b 16.900(17), c 7.968(8) Å, β 96.66(5)° and Z = 4. The ytterbium is pseudo-octahedrally coordinated by a cyclopentadienyl ligand, trans bromines, and mer tetrahydrofuran ligands, and the ytterbium-oxygen distance trans to cyclopentadienyl is longer than the other ytterbium-oxygen bonds. 

Original languageEnglish
Pages (from-to)45-50
Number of pages6
JournalJournal of Organometallic Chemistry
Volume293
Issue number1
DOIs
Publication statusPublished - 17 Sep 1985

Cite this

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title = "Organolanthanoids. VII. The crystal and molecular structure of dibromo-η5-cyclopentadienyltris(tetrahydrofuran)ytterbium(III)",
abstract = "Crystals of dibromo-η5-cyclopentadienyltris(tetrahydrofuran)ytterbium(III) are monoclinic, P21/n (C2n5, No. 14), with a 15.310(15), b 16.900(17), c 7.968(8) {\AA}, β 96.66(5)° and Z = 4. The ytterbium is pseudo-octahedrally coordinated by a cyclopentadienyl ligand, trans bromines, and mer tetrahydrofuran ligands, and the ytterbium-oxygen distance trans to cyclopentadienyl is longer than the other ytterbium-oxygen bonds. ",
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Organolanthanoids. VII. The crystal and molecular structure of dibromo-η5-cyclopentadienyltris(tetrahydrofuran)ytterbium(III). / Deacon, G. B.; Fallon, G. D.; Wilkinson, D. L.

In: Journal of Organometallic Chemistry, Vol. 293, No. 1, 17.09.1985, p. 45-50.

Research output: Contribution to journalArticleResearchpeer-review

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T1 - Organolanthanoids. VII. The crystal and molecular structure of dibromo-η5-cyclopentadienyltris(tetrahydrofuran)ytterbium(III)

AU - Deacon, G. B.

AU - Fallon, G. D.

AU - Wilkinson, D. L.

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N2 - Crystals of dibromo-η5-cyclopentadienyltris(tetrahydrofuran)ytterbium(III) are monoclinic, P21/n (C2n5, No. 14), with a 15.310(15), b 16.900(17), c 7.968(8) Å, β 96.66(5)° and Z = 4. The ytterbium is pseudo-octahedrally coordinated by a cyclopentadienyl ligand, trans bromines, and mer tetrahydrofuran ligands, and the ytterbium-oxygen distance trans to cyclopentadienyl is longer than the other ytterbium-oxygen bonds. 

AB - Crystals of dibromo-η5-cyclopentadienyltris(tetrahydrofuran)ytterbium(III) are monoclinic, P21/n (C2n5, No. 14), with a 15.310(15), b 16.900(17), c 7.968(8) Å, β 96.66(5)° and Z = 4. The ytterbium is pseudo-octahedrally coordinated by a cyclopentadienyl ligand, trans bromines, and mer tetrahydrofuran ligands, and the ytterbium-oxygen distance trans to cyclopentadienyl is longer than the other ytterbium-oxygen bonds. 

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