Organolanthanoid-halide synthons - a new general route to monofunctionalized lanthanoid(II) compounds?

Michal Wiecko; Glen Berenger Deacon; Peter Courtney Junk

doi:10.1039/c0cc01317j

Organolanthanoid-halide synthons - a new general route to monofunctionalized lanthanoid(II) compounds?

Michal Wiecko
, Glen Berenger Deacon
, Peter Courtney Junk

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

28 Citations (Scopus)

Abstract

New EuII and YbII complexes [Ln(Ph2pz)I(thf)4] were synthesized from the corresponding metals and 3,5-diphenylpyrazole (HPh2pz) using iodobenzene as oxidizing agent. In the absence of the pyrazole, the charge separated YbII/YbIII complex [ Yb(dme)4 YbPh4(dme) 2] has been isolated.

Original language	English
Pages (from-to)	5076 - 5078
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	28
DOIs	https://doi.org/10.1039/c0cc01317j
Publication status	Published - 2010

Access to Document

10.1039/c0cc01317j

Cite this

@article{9fb83d8417b24bfc97a678f60acbed0c,

title = "Organolanthanoid-halide synthons - a new general route to monofunctionalized lanthanoid(II) compounds?",

abstract = "New EuII and YbII complexes [Ln(Ph2pz)I(thf)4] were synthesized from the corresponding metals and 3,5-diphenylpyrazole (HPh2pz) using iodobenzene as oxidizing agent. In the absence of the pyrazole, the charge separated YbII/YbIII complex [ Yb(dme)4 YbPh4(dme) 2] has been isolated.",

author = "Michal Wiecko and Deacon, \{Glen Berenger\} and Junk, \{Peter Courtney\}",

year = "2010",

doi = "10.1039/c0cc01317j",

language = "English",

volume = "46",

pages = "5076 -- 5078",

journal = "Chemical Communications",

issn = "1359-7345",