TY - JOUR
T1 - Organoamidometallics-III. 2,6-Dimethylpyridine and 1,4-dioxan as weakly coordinating polar solvents for decarboxylation syntheses of N,N-dimethyl-N′-(polyfluorophenyl)ethane-1,2-diaminato(1-)platinum(II) complexes
AU - Buxton, D. P.
AU - Deacon, G. B.
AU - Black, D. St C
PY - 1989
Y1 - 1989
N2 - The complexes, Pt[N(p-HC6F4)CH2CH2NMe2]X(L)(X = Cl, L = Ph3P; X = I, L = pyrazine) have been prepared by reaction of PtX2(dmen) (dmen = N,N-dimethylethane-1,2-diamine) with TlO2CC6F4H-p, C6F5H and L in hot 2,6-dimethylpyridine (dmpy), and are considered to have L trans to -NMe2. The pyrazine complex was also obtained in very low yield from an analogous synthesis in 1,4-dioxan. Reaction of PtBr2 (dmen) with TlO2CC6F4H-p and C6F5H in 2,6-dimethylpyridine without an added ligand gave a low yield of Pt[N(p-HC6F4)CH2CH2NMe2](O2CC6F4H-p)(dmpy).
AB - The complexes, Pt[N(p-HC6F4)CH2CH2NMe2]X(L)(X = Cl, L = Ph3P; X = I, L = pyrazine) have been prepared by reaction of PtX2(dmen) (dmen = N,N-dimethylethane-1,2-diamine) with TlO2CC6F4H-p, C6F5H and L in hot 2,6-dimethylpyridine (dmpy), and are considered to have L trans to -NMe2. The pyrazine complex was also obtained in very low yield from an analogous synthesis in 1,4-dioxan. Reaction of PtBr2 (dmen) with TlO2CC6F4H-p and C6F5H in 2,6-dimethylpyridine without an added ligand gave a low yield of Pt[N(p-HC6F4)CH2CH2NMe2](O2CC6F4H-p)(dmpy).
UR - http://www.scopus.com/inward/record.url?scp=38249024539&partnerID=8YFLogxK
U2 - 10.1016/S0277-5387(00)86495-5
DO - 10.1016/S0277-5387(00)86495-5
M3 - Article
AN - SCOPUS:38249024539
VL - 8
SP - 143
EP - 147
JO - Polyhedron
JF - Polyhedron
SN - 0277-5387
IS - 2
ER -