One-pot synthesis of PVP-coated Ni0.6Fe2.4O4 nanocrystals

Xian Yong Lu; Mu Niu; Chun Hui Yang; Luo Xin Yi; Rui Rui Qiao; Mei Hong Du; Ming Yuan Gao

doi:10.1007/s11434-010-4054-y

One-pot synthesis of PVP-coated Ni_0.6Fe_2.4O₄ nanocrystals

Xian Yong Lu, Mu Niu, Chun Hui Yang, Luo Xin Yi, Rui Rui Qiao, Mei Hong Du, Ming Yuan Gao

Research output: Contribution to journal › Article › Research › peer-review

5 Citations (Scopus)

Abstract

Novel poly(N-vinyl-2-pyrrolidone) (PVP)-coated nickel ferrite nanocrystals were prepared by simultaneously pyrolyzing nickel(II) acetylacetonate (Ni(acac)₂) and iron(III) acetylacetonate (Fe(acac)₃) in N-vinyl-2-pyrrolidone (NVP). The PVP coating was formed in situ through polymerization of NVP. The crystalline structure of the resultant nickel ferrite was analyzed by high-resolution transmission electron microscopy, electron diffraction patterns, and powder X-ray diffraction. In addition, the valence state of Ni and the metal contents of Ni and Fe in different valence states were analyzed by X-ray photoelectron spectroscopy (XPS), atomic absorption and the phenanthroline method. The surface coating layer of PVP and its binding states were characterized by Fourier transform infrared spectroscopy in combination with XPS. Colloidal stability experiments revealed that the nanocrystals could be dispersed well in both phosphate-buffered saline and Dulbecco's Modified Eagle Medium.

Original language	English
Pages (from-to)	3472-3478
Number of pages	7
Journal	Chinese Science Bulletin
Volume	55
Issue number	30
DOIs	https://doi.org/10.1007/s11434-010-4054-y
Publication status	Published - Oct 2010
Externally published	Yes

Keywords

colloidal stability
magnetic nanocrystals
N-vinyl-2-pyrrolidone
thermal decomposition

Access to Document

10.1007/s11434-010-4054-y

Cite this

@article{7c645b43b93f487a8d6640536f9c3871,

title = "One-pot synthesis of PVP-coated Ni0.6Fe2.4O4 nanocrystals",

abstract = "Novel poly(N-vinyl-2-pyrrolidone) (PVP)-coated nickel ferrite nanocrystals were prepared by simultaneously pyrolyzing nickel(II) acetylacetonate (Ni(acac)2) and iron(III) acetylacetonate (Fe(acac)3) in N-vinyl-2-pyrrolidone (NVP). The PVP coating was formed in situ through polymerization of NVP. The crystalline structure of the resultant nickel ferrite was analyzed by high-resolution transmission electron microscopy, electron diffraction patterns, and powder X-ray diffraction. In addition, the valence state of Ni and the metal contents of Ni and Fe in different valence states were analyzed by X-ray photoelectron spectroscopy (XPS), atomic absorption and the phenanthroline method. The surface coating layer of PVP and its binding states were characterized by Fourier transform infrared spectroscopy in combination with XPS. Colloidal stability experiments revealed that the nanocrystals could be dispersed well in both phosphate-buffered saline and Dulbecco's Modified Eagle Medium.",

keywords = "colloidal stability, magnetic nanocrystals, N-vinyl-2-pyrrolidone, thermal decomposition",

author = "Lu, \{Xian Yong\} and Mu Niu and Yang, \{Chun Hui\} and Yi, \{Luo Xin\} and Qiao, \{Rui Rui\} and Du, \{Mei Hong\} and Gao, \{Ming Yuan\}",

year = "2010",

month = oct,

doi = "10.1007/s11434-010-4054-y",

language = "English",

volume = "55",

pages = "3472--3478",

journal = "Chinese Science Bulletin",

issn = "1001-6538",

publisher = "Elsevier",

number = "30",

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TY - JOUR

T1 - One-pot synthesis of PVP-coated Ni0.6Fe2.4O4 nanocrystals

AU - Lu, Xian Yong

AU - Niu, Mu

AU - Yang, Chun Hui

AU - Yi, Luo Xin

AU - Qiao, Rui Rui

AU - Du, Mei Hong

AU - Gao, Ming Yuan

PY - 2010/10

Y1 - 2010/10

N2 - Novel poly(N-vinyl-2-pyrrolidone) (PVP)-coated nickel ferrite nanocrystals were prepared by simultaneously pyrolyzing nickel(II) acetylacetonate (Ni(acac)2) and iron(III) acetylacetonate (Fe(acac)3) in N-vinyl-2-pyrrolidone (NVP). The PVP coating was formed in situ through polymerization of NVP. The crystalline structure of the resultant nickel ferrite was analyzed by high-resolution transmission electron microscopy, electron diffraction patterns, and powder X-ray diffraction. In addition, the valence state of Ni and the metal contents of Ni and Fe in different valence states were analyzed by X-ray photoelectron spectroscopy (XPS), atomic absorption and the phenanthroline method. The surface coating layer of PVP and its binding states were characterized by Fourier transform infrared spectroscopy in combination with XPS. Colloidal stability experiments revealed that the nanocrystals could be dispersed well in both phosphate-buffered saline and Dulbecco's Modified Eagle Medium.

AB - Novel poly(N-vinyl-2-pyrrolidone) (PVP)-coated nickel ferrite nanocrystals were prepared by simultaneously pyrolyzing nickel(II) acetylacetonate (Ni(acac)2) and iron(III) acetylacetonate (Fe(acac)3) in N-vinyl-2-pyrrolidone (NVP). The PVP coating was formed in situ through polymerization of NVP. The crystalline structure of the resultant nickel ferrite was analyzed by high-resolution transmission electron microscopy, electron diffraction patterns, and powder X-ray diffraction. In addition, the valence state of Ni and the metal contents of Ni and Fe in different valence states were analyzed by X-ray photoelectron spectroscopy (XPS), atomic absorption and the phenanthroline method. The surface coating layer of PVP and its binding states were characterized by Fourier transform infrared spectroscopy in combination with XPS. Colloidal stability experiments revealed that the nanocrystals could be dispersed well in both phosphate-buffered saline and Dulbecco's Modified Eagle Medium.

KW - colloidal stability

KW - magnetic nanocrystals

KW - N-vinyl-2-pyrrolidone

KW - thermal decomposition

UR - https://www.scopus.com/pages/publications/78349262649

U2 - 10.1007/s11434-010-4054-y

DO - 10.1007/s11434-010-4054-y

M3 - Article

AN - SCOPUS:78349262649

SN - 1001-6538

VL - 55

SP - 3472

EP - 3478

JO - Chinese Science Bulletin

JF - Chinese Science Bulletin

IS - 30