One-electron reduction of an "extended viologen" p-phenylene-bis-4,4'-(1-aryl-2,6-diphenylpyridinium) dication

Alison Funston; James Kirby; John Miller; Lubomir Pospisil; Jan Fiedler; Magdalena Hromadova; Miroslav Gal; Jaroslav Pecka; Michal Valasek; Zbigniew Zawada; Pawel Rempala; Josef Michl

doi:10.1021/jp053556n

One-electron reduction of an "extended viologen" p-phenylene-bis-4,4'-(1-aryl-2,6-diphenylpyridinium) dication

Alison Funston
, James Kirby
, John Miller
, Lubomir Pospisil
, Jan Fiedler
, Magdalena Hromadova
, Miroslav Gal
, Jaroslav Pecka
, Michal Valasek
, Zbigniew Zawada
, Pawel Rempala
, Josef Michl

Research output: Contribution to journal › Article › Research › peer-review

43 Citations (Scopus)

Abstract

One-electron reduction of the extended viologen dication I yields the red cation radical 2, characterized by strong near-IR absorption. It has been generated and studied by pulse radiolytic, electrochemical, redox titration, UV-visible, and electron paramagnetic resonance spectroscopic methods. All results are in agreement with a fully delocalized electronic structure for 2.

Original language	English
Pages (from-to)	10862 - 10869
Number of pages	8
Journal	The Journal of Physical Chemistry A
Volume	109
Issue number	48
DOIs	https://doi.org/10.1021/jp053556n
Publication status	Published - 2005
Externally published	Yes

Access to Document

10.1021/jp053556n

Cite this

@article{daebde9bc3314fdf9595048a6437f19c,

title = "One-electron reduction of an {"}extended viologen{"} p-phenylene-bis-4,4'-(1-aryl-2,6-diphenylpyridinium) dication",

abstract = "One-electron reduction of the extended viologen dication I yields the red cation radical 2, characterized by strong near-IR absorption. It has been generated and studied by pulse radiolytic, electrochemical, redox titration, UV-visible, and electron paramagnetic resonance spectroscopic methods. All results are in agreement with a fully delocalized electronic structure for 2.",

author = "Alison Funston and James Kirby and John Miller and Lubomir Pospisil and Jan Fiedler and Magdalena Hromadova and Miroslav Gal and Jaroslav Pecka and Michal Valasek and Zbigniew Zawada and Pawel Rempala and Josef Michl",

year = "2005",

doi = "10.1021/jp053556n",

language = "English",

volume = "109",

pages = "10862 -- 10869",

journal = "The Journal of Physical Chemistry A",

issn = "1089-5639",

publisher = "American Chemical Society",

number = "48",

}

TY - JOUR

T1 - One-electron reduction of an "extended viologen" p-phenylene-bis-4,4'-(1-aryl-2,6-diphenylpyridinium) dication

AU - Funston, Alison

AU - Kirby, James

AU - Miller, John

AU - Pospisil, Lubomir

AU - Fiedler, Jan

AU - Hromadova, Magdalena

AU - Gal, Miroslav

AU - Pecka, Jaroslav

AU - Valasek, Michal

AU - Zawada, Zbigniew

AU - Rempala, Pawel

AU - Michl, Josef

PY - 2005

Y1 - 2005

N2 - One-electron reduction of the extended viologen dication I yields the red cation radical 2, characterized by strong near-IR absorption. It has been generated and studied by pulse radiolytic, electrochemical, redox titration, UV-visible, and electron paramagnetic resonance spectroscopic methods. All results are in agreement with a fully delocalized electronic structure for 2.

AB - One-electron reduction of the extended viologen dication I yields the red cation radical 2, characterized by strong near-IR absorption. It has been generated and studied by pulse radiolytic, electrochemical, redox titration, UV-visible, and electron paramagnetic resonance spectroscopic methods. All results are in agreement with a fully delocalized electronic structure for 2.

UR - http://www.scopus.com/record/display.url?eid=2-s2.0-29444454613&origin=inward&txGid=n-WOVf_1I2CffHwColPcQhh%3a13

U2 - 10.1021/jp053556n

DO - 10.1021/jp053556n

M3 - Article

SN - 1089-5639

VL - 109

SP - 10862

EP - 10869

JO - The Journal of Physical Chemistry A

JF - The Journal of Physical Chemistry A

IS - 48

ER -

One-electron reduction of an "extended viologen" p-phenylene-bis-4,4'-(1-aryl-2,6-diphenylpyridinium) dication

Abstract

Access to Document

Other files and links

Cite this