One-dimensional CoS2-MoS2                                                  nano-flakes decorated MoO2                                                  sub-micro-wires for synergistically enhanced hydrogen evolution

Yang Wang; Yinlong Zhu; Sepideh Afshar; Meng Wai Woo; Jing Tang; Timothy  Williams; Biao Kong; Dongyuan Zhao; Huanting Wang; Cordelia Selomulya

doi:10.1039/c8nr08418a

One-dimensional CoS₂-MoS₂ nano-flakes decorated MoO₂ sub-micro-wires for synergistically enhanced hydrogen evolution

Yang Wang, Yinlong Zhu, Sepideh Afshar, Meng Wai Woo, Jing Tang, Timothy Williams, Biao Kong, Dongyuan Zhao, Huanting Wang, Cordelia Selomulya

Research output: Contribution to journal › Article › Research › peer-review

25 Citations (Scopus)

Abstract

CoS ₂ -MoS ₂ nanoflakes decorated MoO ₂ (CoMoOS) hybrid submicro-wires with rich active interfaces were synthesized via the sulfuration of CoMoO ₄ . They showed excellent activity while synergistically catalyzing the hydrogen evolultion reaction (HER) in basic media by promoting both the water dissociation and hydrogen absorption steps. Thus, the CoMoOS catalysts only needed 123 mV to achieve 10 mA cm ^-2 with a small Tafel slope in alkaline solutions, and required 1.68 V to obtain the same current density when assembled into an alkaline electrolyser.

Original language	English
Pages (from-to)	3500-3505
Number of pages	6
Journal	Nanoscale
Volume	11
Issue number	8
DOIs	https://doi.org/10.1039/c8nr08418a
Publication status	Published - 28 Feb 2019

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10.1039/c8nr08418a

261082890-AAMAccepted author manuscript, 773 KB

Cite this

Wang, Y., Zhu, Y., Afshar, S., Woo, M. W., Tang, J., Williams, T., Kong, B., Zhao, D., Wang, H., & Selomulya, C. (2019). One-dimensional CoS₂-MoS₂ nano-flakes decorated MoO₂ sub-micro-wires for synergistically enhanced hydrogen evolution. Nanoscale, 11(8), 3500-3505. https://doi.org/10.1039/c8nr08418a

@article{1511a65717bc440190f8ae79f5a6cebe,

title = "One-dimensional CoS2-MoS2 nano-flakes decorated MoO2 sub-micro-wires for synergistically enhanced hydrogen evolution",

abstract = " CoS 2 -MoS 2 nanoflakes decorated MoO 2 (CoMoOS) hybrid submicro-wires with rich active interfaces were synthesized via the sulfuration of CoMoO 4 . They showed excellent activity while synergistically catalyzing the hydrogen evolultion reaction (HER) in basic media by promoting both the water dissociation and hydrogen absorption steps. Thus, the CoMoOS catalysts only needed 123 mV to achieve 10 mA cm -2 with a small Tafel slope in alkaline solutions, and required 1.68 V to obtain the same current density when assembled into an alkaline electrolyser. ",

author = "Yang Wang and Yinlong Zhu and Sepideh Afshar and Woo, {Meng Wai} and Jing Tang and Timothy Williams and Biao Kong and Dongyuan Zhao and Huanting Wang and Cordelia Selomulya",

year = "2019",

month = feb,

day = "28",

doi = "10.1039/c8nr08418a",

language = "English",

volume = "11",

pages = "3500--3505",

journal = "Nanoscale",

issn = "2040-3364",

publisher = "The Royal Society of Chemistry",

number = "8",

}

Wang, Y, Zhu, Y, Afshar, S, Woo, MW, Tang, J, Williams, T, Kong, B, Zhao, D , Wang, H & Selomulya, C 2019, 'One-dimensional CoS₂-MoS₂ nano-flakes decorated MoO₂ sub-micro-wires for synergistically enhanced hydrogen evolution', Nanoscale, vol. 11, no. 8, pp. 3500-3505. https://doi.org/10.1039/c8nr08418a

One-dimensional CoS₂-MoS₂ nano-flakes decorated MoO₂ sub-micro-wires for synergistically enhanced hydrogen evolution. / Wang, Yang; Zhu, Yinlong; Afshar, Sepideh et al.

In: Nanoscale, Vol. 11, No. 8, 28.02.2019, p. 3500-3505.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - One-dimensional CoS2-MoS2 nano-flakes decorated MoO2 sub-micro-wires for synergistically enhanced hydrogen evolution

AU - Wang, Yang

AU - Zhu, Yinlong

AU - Afshar, Sepideh

AU - Woo, Meng Wai

AU - Tang, Jing

AU - Williams, Timothy

AU - Kong, Biao

AU - Zhao, Dongyuan

AU - Wang, Huanting

AU - Selomulya, Cordelia

PY - 2019/2/28

Y1 - 2019/2/28

N2 - CoS 2 -MoS 2 nanoflakes decorated MoO 2 (CoMoOS) hybrid submicro-wires with rich active interfaces were synthesized via the sulfuration of CoMoO 4 . They showed excellent activity while synergistically catalyzing the hydrogen evolultion reaction (HER) in basic media by promoting both the water dissociation and hydrogen absorption steps. Thus, the CoMoOS catalysts only needed 123 mV to achieve 10 mA cm -2 with a small Tafel slope in alkaline solutions, and required 1.68 V to obtain the same current density when assembled into an alkaline electrolyser.

AB - CoS 2 -MoS 2 nanoflakes decorated MoO 2 (CoMoOS) hybrid submicro-wires with rich active interfaces were synthesized via the sulfuration of CoMoO 4 . They showed excellent activity while synergistically catalyzing the hydrogen evolultion reaction (HER) in basic media by promoting both the water dissociation and hydrogen absorption steps. Thus, the CoMoOS catalysts only needed 123 mV to achieve 10 mA cm -2 with a small Tafel slope in alkaline solutions, and required 1.68 V to obtain the same current density when assembled into an alkaline electrolyser.

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U2 - 10.1039/c8nr08418a

DO - 10.1039/c8nr08418a

M3 - Article

C2 - 30741297

AN - SCOPUS:85061966074

VL - 11

SP - 3500

EP - 3505

JO - Nanoscale

JF - Nanoscale

SN - 2040-3364

IS - 8

ER -

One-dimensional CoS₂-MoS₂ nano-flakes decorated MoO₂ sub-micro-wires for synergistically enhanced hydrogen evolution

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Advanced in-situ electron microscope facility for research in alloys, nanomaterials, functional materials, magnetic materials and minerals

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One-dimensional CoS2-MoS2 nano-flakes decorated MoO2 sub-micro-wires for synergistically enhanced hydrogen evolution

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Advanced in-situ electron microscope facility for research in alloys, nanomaterials, functional materials, magnetic materials and minerals

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Centre for Electron Microscopy (MCEM)

X-ray Platform (MXP)

Cite this

One-dimensional CoS₂-MoS₂ nano-flakes decorated MoO₂ sub-micro-wires for synergistically enhanced hydrogen evolution