Octylgermane on gold: Synthesis, oxidation, and pattern formation

Thomas M. Owens; Bonnie J. Ludwig; Daniel R. Fosnacht; Jeffrey M. Bartolin; Natalie Homann; Norman J. Wells; Bradford G. Orr; Mark M. Banaszak Holl

doi:10.1021/la0490846

Octylgermane on gold: Synthesis, oxidation, and pattern formation

Thomas M. Owens, Bonnie J. Ludwig, Daniel R. Fosnacht, Jeffrey M. Bartolin, Natalie Homann, Norman J. Wells, Bradford G. Orr, Mark M. Banaszak Holl

Research output: Contribution to journal › Article › Research › peer-review

2 Citations (Scopus)

Abstract

Chemisorbed monolayers of octylgermane (C ₈H ₁₇GeH ₃) on gold have been formed by vapor deposition in ultrahigh vacuum. The monolayer has been characterized by X-ray photoelectron and reflection absorption infrared spectroscopies (XPS and RAIRS) and scanning tunneling microscopy (STM). XPS data indicate the monolayer can be oxidized by exposure to ozone. STM images exhibit a complex pattern which can be modeled as strain-mediated spinodal decomposition.

Original language	English
Pages (from-to)	11422-11427
Number of pages	6
Journal	Langmuir
Volume	20
Issue number	26
DOIs	https://doi.org/10.1021/la0490846
Publication status	Published - 21 Dec 2004
Externally published	Yes

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abstract = "Chemisorbed monolayers of octylgermane (C 8H 17GeH 3) on gold have been formed by vapor deposition in ultrahigh vacuum. The monolayer has been characterized by X-ray photoelectron and reflection absorption infrared spectroscopies (XPS and RAIRS) and scanning tunneling microscopy (STM). XPS data indicate the monolayer can be oxidized by exposure to ozone. STM images exhibit a complex pattern which can be modeled as strain-mediated spinodal decomposition.",

author = "Owens, {Thomas M.} and Ludwig, {Bonnie J.} and Fosnacht, {Daniel R.} and Bartolin, {Jeffrey M.} and Natalie Homann and Wells, {Norman J.} and Orr, {Bradford G.} and {Banaszak Holl}, {Mark M.}",

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AU - Owens, Thomas M.

AU - Ludwig, Bonnie J.

AU - Fosnacht, Daniel R.

AU - Bartolin, Jeffrey M.

AU - Homann, Natalie

AU - Wells, Norman J.

AU - Orr, Bradford G.

AU - Banaszak Holl, Mark M.

PY - 2004/12/21

Y1 - 2004/12/21

N2 - Chemisorbed monolayers of octylgermane (C 8H 17GeH 3) on gold have been formed by vapor deposition in ultrahigh vacuum. The monolayer has been characterized by X-ray photoelectron and reflection absorption infrared spectroscopies (XPS and RAIRS) and scanning tunneling microscopy (STM). XPS data indicate the monolayer can be oxidized by exposure to ozone. STM images exhibit a complex pattern which can be modeled as strain-mediated spinodal decomposition.

AB - Chemisorbed monolayers of octylgermane (C 8H 17GeH 3) on gold have been formed by vapor deposition in ultrahigh vacuum. The monolayer has been characterized by X-ray photoelectron and reflection absorption infrared spectroscopies (XPS and RAIRS) and scanning tunneling microscopy (STM). XPS data indicate the monolayer can be oxidized by exposure to ozone. STM images exhibit a complex pattern which can be modeled as strain-mediated spinodal decomposition.

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Octylgermane on gold: Synthesis, oxidation, and pattern formation

Abstract

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