Observation of Anomalous g-value Temperature Dependence of the ESR Spectrum of Fe(III)

George Lazarev, Tunay Ersez, F Lara, R Moreno-Espara

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    Abstract

    Large isotropic shifts of the g-value in the ESR spectrum of Fe(III) as an impurity in a sample of ferrous spin-crossover complex (tetrakis(2-pyridylmethyl)ethylenediamine)iron(II)perchlorate in the range 4-370 K were detected as a function of temperature. New antiferromagnetic phase at T < 20 K was discovered using SQUID magnetometer.
    Original languageEnglish
    Pages (from-to)19-24
    Number of pages6
    JournalApplied Magnetic Resonance
    Volume14
    Issue number1
    DOIs
    Publication statusPublished - 1998

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