Abstract
Ligands resulting from the transition-metal-promoted nucleophilic addition of water or an alcohol to dicyanonitrosomethanide ions (dcnm) have been utilised in the formation of a large series of polynuclear complexes. Addition of water to dcnm results in formation of carbarnoylcyanonitrosomethanide (ccnm); deprotonation of this ligand gives amidocarbonyl(cyano)nitrosomethanide (acnm), which has been incorporated into the trinuclear complex [Cu-3(acnm)(2)(dmae)(2)(H2O)(2)] [dmae = 2-(dimethylamino)ethoxide] (1) which shows strong antiferromagnetic coupling with an exchange coupling constant, J = -500 cm(-1).
Original language | English |
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Pages (from-to) | 59 - 73 |
Number of pages | 15 |
Journal | European Journal of Inorganic Chemistry |
Issue number | 1 |
DOIs | |
Publication status | Published - 2010 |