N,S-Dimethyldithiocarbamyl oxalates as precursors for determining kinetic parameters for oxyacyl radicals

Sara H. Kyne, Carl H. Schiesser

Research output: Contribution to journalArticleResearchpeer-review

5 Citations (Scopus)

Abstract

N,S-Dimethyldithiocarbamyl oxalates (e.g.6, 10) are novel, readily prepared precursors to alkyloxyacyl radicals 1 that are more suitable for kinetic studies than existing precursors; 10 has allowed the determination of accurate rate data for the cyclization of the butenyloxyacyl radical 5 (kc = 1.2 × 107 s-1 at 21 °C). 

Original languageEnglish
Pages (from-to)12040-12042
Number of pages3
JournalChemical Communications
Volume50
Issue number81
DOIs
Publication statusPublished - 18 Oct 2014
Externally publishedYes

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