N,S-Dimethyldithiocarbamyl oxalates as precursors for determining kinetic parameters for oxyacyl radicals

Sara H. Kyne; Carl H. Schiesser

doi:10.1039/c4cc06132b

N,S-Dimethyldithiocarbamyl oxalates as precursors for determining kinetic parameters for oxyacyl radicals

Sara H. Kyne, Carl H. Schiesser

Research output: Contribution to journal › Article › Research › peer-review

6 Citations (Scopus)

Abstract

N,S-Dimethyldithiocarbamyl oxalates (e.g.6, 10) are novel, readily prepared precursors to alkyloxyacyl radicals 1 that are more suitable for kinetic studies than existing precursors; 10 has allowed the determination of accurate rate data for the cyclization of the butenyloxyacyl radical 5 (k_c = 1.2 × 10⁷ s^-1 at 21 °C).

Original language	English
Pages (from-to)	12040-12042
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	81
DOIs	https://doi.org/10.1039/c4cc06132b
Publication status	Published - 18 Oct 2014
Externally published	Yes

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10.1039/c4cc06132b

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title = "N,S-Dimethyldithiocarbamyl oxalates as precursors for determining kinetic parameters for oxyacyl radicals",

abstract = "N,S-Dimethyldithiocarbamyl oxalates (e.g.6, 10) are novel, readily prepared precursors to alkyloxyacyl radicals 1 that are more suitable for kinetic studies than existing precursors; 10 has allowed the determination of accurate rate data for the cyclization of the butenyloxyacyl radical 5 (kc = 1.2 × 107 s-1 at 21 °C). ",

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doi = "10.1039/c4cc06132b",

language = "English",

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AU - Schiesser, Carl H.

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N2 - N,S-Dimethyldithiocarbamyl oxalates (e.g.6, 10) are novel, readily prepared precursors to alkyloxyacyl radicals 1 that are more suitable for kinetic studies than existing precursors; 10 has allowed the determination of accurate rate data for the cyclization of the butenyloxyacyl radical 5 (kc = 1.2 × 107 s-1 at 21 °C).

AB - N,S-Dimethyldithiocarbamyl oxalates (e.g.6, 10) are novel, readily prepared precursors to alkyloxyacyl radicals 1 that are more suitable for kinetic studies than existing precursors; 10 has allowed the determination of accurate rate data for the cyclization of the butenyloxyacyl radical 5 (kc = 1.2 × 107 s-1 at 21 °C).

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U2 - 10.1039/c4cc06132b

DO - 10.1039/c4cc06132b

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C2 - 25171586

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JF - Chemical Communications

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ER -

N,S-Dimethyldithiocarbamyl oxalates as precursors for determining kinetic parameters for oxyacyl radicals

Abstract

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ARC Centre of Excellence - Centre for Free Radical Chemistry and Biotechnology

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N,S-Dimethyldithiocarbamyl oxalates as precursors for determining kinetic parameters for oxyacyl radicals

Abstract

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Projects

ARC Centre of Excellence - Centre for Free Radical Chemistry and Biotechnology

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