Novel Synthesis Techniques for Preparation of Ultrahigh-Crystalline Vanadyl Pyrophosphate as a Highly Selective Catalyst for n-Butane Oxidation

Ali Asghar Rownaghi, Yun Hin Taufiq-Yap

Research output: Contribution to journalArticleResearchpeer-review

Abstract

The vanadyl hydrogen phosphate hemihydrate (VOHPO4·0.5H2O), with well-defined crystal size, has been successfully synthesized for the first time, using a simple one-step solvothermal process that was free of surfactants and water and had a short reaction time and low temperature. The synthesis was performed via the reaction of V2O5 and H3PO4 with an aliphatic alcohol (1-propanol or 1-butanol) at high temperatures (373, 393, and 423 K) in a high-pressure autoclave. The mixture of reactions directly gave the VOHPO4·0.5H2O, which is a valuable commercial catalyst precursor for the selective oxidation of n-butane to maleic anhydride. The catalyst precursors were dried by microwave irradiation. The reaction conditions (by varying the reducing agent and reaction temperature) were used further for optimization of the crystallite size, surface area, morphology, and activity of the nanostructure of vanadium phosphate oxide [(VO)2P2O7] catalyst. This new method significantly reduced the preparation time and lowered the production temperature (50%) of catalyst precursor (VOHPO4·0.5H2O), when compared to conventional hydrothermal synthesis methods. The as-prepared (VO)2P2O7 catalyst under various conditions exhibited remarkably different physical and chemical properties, indicating the potential of the suggested method in tuning the crystalline structure and surface area of (VO)2P2O7 to improve its catalytic performance. It was found that the length of the carbon chain in an alcohol and reaction temperature in the solvothermal condition had a great impact on the chemical and physical properties of resulting catalysts. Interestingly, there was no trace of VO(H2PO4)2, which is an impurity noted to be readily formed under solvothermal preparation conditions. The precursors and catalysts were characterized using a combination of powder X-ray diffraction (XRD), Brunauer−Emmett−Teller (BET) surface area measurement, scanning electron microscopy (SEM), and temperature-programmed reduction in hydrogen (H2-TPR). A correlation between the surface area of the catalyst and the activity was observed. Finally, the yield of maleic anhydride was significantly increased from 21% for conventional catalyst to 38% for the new solvothermal catalyst.
Original languageEnglish
Pages (from-to)2135 - 2143
Number of pages9
JournalIndustrial and Engineering Chemistry Research
Volume49
Issue number5
DOIs
Publication statusPublished - 2010

Cite this

@article{35599ec2a3684f64afbad329c6efbec6,
title = "Novel Synthesis Techniques for Preparation of Ultrahigh-Crystalline Vanadyl Pyrophosphate as a Highly Selective Catalyst for n-Butane Oxidation",
abstract = "The vanadyl hydrogen phosphate hemihydrate (VOHPO4·0.5H2O), with well-defined crystal size, has been successfully synthesized for the first time, using a simple one-step solvothermal process that was free of surfactants and water and had a short reaction time and low temperature. The synthesis was performed via the reaction of V2O5 and H3PO4 with an aliphatic alcohol (1-propanol or 1-butanol) at high temperatures (373, 393, and 423 K) in a high-pressure autoclave. The mixture of reactions directly gave the VOHPO4·0.5H2O, which is a valuable commercial catalyst precursor for the selective oxidation of n-butane to maleic anhydride. The catalyst precursors were dried by microwave irradiation. The reaction conditions (by varying the reducing agent and reaction temperature) were used further for optimization of the crystallite size, surface area, morphology, and activity of the nanostructure of vanadium phosphate oxide [(VO)2P2O7] catalyst. This new method significantly reduced the preparation time and lowered the production temperature (50{\%}) of catalyst precursor (VOHPO4·0.5H2O), when compared to conventional hydrothermal synthesis methods. The as-prepared (VO)2P2O7 catalyst under various conditions exhibited remarkably different physical and chemical properties, indicating the potential of the suggested method in tuning the crystalline structure and surface area of (VO)2P2O7 to improve its catalytic performance. It was found that the length of the carbon chain in an alcohol and reaction temperature in the solvothermal condition had a great impact on the chemical and physical properties of resulting catalysts. Interestingly, there was no trace of VO(H2PO4)2, which is an impurity noted to be readily formed under solvothermal preparation conditions. The precursors and catalysts were characterized using a combination of powder X-ray diffraction (XRD), Brunauer−Emmett−Teller (BET) surface area measurement, scanning electron microscopy (SEM), and temperature-programmed reduction in hydrogen (H2-TPR). A correlation between the surface area of the catalyst and the activity was observed. Finally, the yield of maleic anhydride was significantly increased from 21{\%} for conventional catalyst to 38{\%} for the new solvothermal catalyst.",
author = "Rownaghi, {Ali Asghar} and Taufiq-Yap, {Yun Hin}",
year = "2010",
doi = "10.1021/ie902011a",
language = "English",
volume = "49",
pages = "2135 -- 2143",
journal = "Industrial and Engineering Chemistry Research",
issn = "0888-5885",
number = "5",

}

Novel Synthesis Techniques for Preparation of Ultrahigh-Crystalline Vanadyl Pyrophosphate as a Highly Selective Catalyst for n-Butane Oxidation. / Rownaghi, Ali Asghar; Taufiq-Yap, Yun Hin.

In: Industrial and Engineering Chemistry Research, Vol. 49, No. 5, 2010, p. 2135 - 2143.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Novel Synthesis Techniques for Preparation of Ultrahigh-Crystalline Vanadyl Pyrophosphate as a Highly Selective Catalyst for n-Butane Oxidation

AU - Rownaghi, Ali Asghar

AU - Taufiq-Yap, Yun Hin

PY - 2010

Y1 - 2010

N2 - The vanadyl hydrogen phosphate hemihydrate (VOHPO4·0.5H2O), with well-defined crystal size, has been successfully synthesized for the first time, using a simple one-step solvothermal process that was free of surfactants and water and had a short reaction time and low temperature. The synthesis was performed via the reaction of V2O5 and H3PO4 with an aliphatic alcohol (1-propanol or 1-butanol) at high temperatures (373, 393, and 423 K) in a high-pressure autoclave. The mixture of reactions directly gave the VOHPO4·0.5H2O, which is a valuable commercial catalyst precursor for the selective oxidation of n-butane to maleic anhydride. The catalyst precursors were dried by microwave irradiation. The reaction conditions (by varying the reducing agent and reaction temperature) were used further for optimization of the crystallite size, surface area, morphology, and activity of the nanostructure of vanadium phosphate oxide [(VO)2P2O7] catalyst. This new method significantly reduced the preparation time and lowered the production temperature (50%) of catalyst precursor (VOHPO4·0.5H2O), when compared to conventional hydrothermal synthesis methods. The as-prepared (VO)2P2O7 catalyst under various conditions exhibited remarkably different physical and chemical properties, indicating the potential of the suggested method in tuning the crystalline structure and surface area of (VO)2P2O7 to improve its catalytic performance. It was found that the length of the carbon chain in an alcohol and reaction temperature in the solvothermal condition had a great impact on the chemical and physical properties of resulting catalysts. Interestingly, there was no trace of VO(H2PO4)2, which is an impurity noted to be readily formed under solvothermal preparation conditions. The precursors and catalysts were characterized using a combination of powder X-ray diffraction (XRD), Brunauer−Emmett−Teller (BET) surface area measurement, scanning electron microscopy (SEM), and temperature-programmed reduction in hydrogen (H2-TPR). A correlation between the surface area of the catalyst and the activity was observed. Finally, the yield of maleic anhydride was significantly increased from 21% for conventional catalyst to 38% for the new solvothermal catalyst.

AB - The vanadyl hydrogen phosphate hemihydrate (VOHPO4·0.5H2O), with well-defined crystal size, has been successfully synthesized for the first time, using a simple one-step solvothermal process that was free of surfactants and water and had a short reaction time and low temperature. The synthesis was performed via the reaction of V2O5 and H3PO4 with an aliphatic alcohol (1-propanol or 1-butanol) at high temperatures (373, 393, and 423 K) in a high-pressure autoclave. The mixture of reactions directly gave the VOHPO4·0.5H2O, which is a valuable commercial catalyst precursor for the selective oxidation of n-butane to maleic anhydride. The catalyst precursors were dried by microwave irradiation. The reaction conditions (by varying the reducing agent and reaction temperature) were used further for optimization of the crystallite size, surface area, morphology, and activity of the nanostructure of vanadium phosphate oxide [(VO)2P2O7] catalyst. This new method significantly reduced the preparation time and lowered the production temperature (50%) of catalyst precursor (VOHPO4·0.5H2O), when compared to conventional hydrothermal synthesis methods. The as-prepared (VO)2P2O7 catalyst under various conditions exhibited remarkably different physical and chemical properties, indicating the potential of the suggested method in tuning the crystalline structure and surface area of (VO)2P2O7 to improve its catalytic performance. It was found that the length of the carbon chain in an alcohol and reaction temperature in the solvothermal condition had a great impact on the chemical and physical properties of resulting catalysts. Interestingly, there was no trace of VO(H2PO4)2, which is an impurity noted to be readily formed under solvothermal preparation conditions. The precursors and catalysts were characterized using a combination of powder X-ray diffraction (XRD), Brunauer−Emmett−Teller (BET) surface area measurement, scanning electron microscopy (SEM), and temperature-programmed reduction in hydrogen (H2-TPR). A correlation between the surface area of the catalyst and the activity was observed. Finally, the yield of maleic anhydride was significantly increased from 21% for conventional catalyst to 38% for the new solvothermal catalyst.

UR - http://pubs.acs.org.ezproxy.lib.monash.edu.au

U2 - 10.1021/ie902011a

DO - 10.1021/ie902011a

M3 - Article

VL - 49

SP - 2135

EP - 2143

JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

SN - 0888-5885

IS - 5

ER -