Novel comb polymers from alternating N-acylated poly(aminoester)s obtained by spontaneous zwitterionic copolymerisation

Kristian Kempe; Patrick A J M De Jongh; Athina Anastasaki; Paul Wilson; David M. Haddleton

doi:10.1039/c5cc07247f

Novel comb polymers from alternating N-acylated poly(aminoester)s obtained by spontaneous zwitterionic copolymerisation

Kristian Kempe, Patrick A J M De Jongh, Athina Anastasaki, Paul Wilson, David M. Haddleton

Research output: Contribution to journal › Article › Research › peer-review

26 Citations (Scopus)

Abstract

N-Acylated poly(aminoester) (NPAE) macromonomers were synthesised via spontaneous copolymerisation of 2-oxazolines and acrylic acid. Inherent quantitative introduction of α-vinyl end-groups was observed, which enabled the preparation of a series of well-defined NPAE comb polymers through redox-initiated RAFT polymerisation. Investigations of the thermal properties of the comb polymers revealed similarities to poly(2-oxazoline) based systems.

Original language	English
Pages (from-to)	16213-16216
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	90
DOIs	https://doi.org/10.1039/c5cc07247f
Publication status	Published - 2015
Externally published	Yes

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abstract = "N-Acylated poly(aminoester) (NPAE) macromonomers were synthesised via spontaneous copolymerisation of 2-oxazolines and acrylic acid. Inherent quantitative introduction of α-vinyl end-groups was observed, which enabled the preparation of a series of well-defined NPAE comb polymers through redox-initiated RAFT polymerisation. Investigations of the thermal properties of the comb polymers revealed similarities to poly(2-oxazoline) based systems.",

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AU - De Jongh, Patrick A J M

AU - Anastasaki, Athina

AU - Wilson, Paul

AU - Haddleton, David M.

PY - 2015

Y1 - 2015

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AB - N-Acylated poly(aminoester) (NPAE) macromonomers were synthesised via spontaneous copolymerisation of 2-oxazolines and acrylic acid. Inherent quantitative introduction of α-vinyl end-groups was observed, which enabled the preparation of a series of well-defined NPAE comb polymers through redox-initiated RAFT polymerisation. Investigations of the thermal properties of the comb polymers revealed similarities to poly(2-oxazoline) based systems.

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JO - Chemical Communications

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Novel comb polymers from alternating N-acylated poly(aminoester)s obtained by spontaneous zwitterionic copolymerisation

Abstract

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