Non-aqueous microwave-assisted syntheses of deca- and hexa-molybdovanadates

Samuel Spillane, Rupali Sharma, Athanasios Zavras, Roger Mulder, Andy Ohlin, Lars Goerigk, Richard A J O'Hair, Chris Ritchie

Research output: Contribution to journalArticleResearchpeer-review

15 Citations (Scopus)

Abstract

We report a new approach for the synthesis of heterohexa- and heterodecametalates via the use of non-aqueous, microwave-assisted reaction conditions. The two novel molybdovanadates have been isolated and characterized in the solid and solution states using single-crystal X-ray diffraction, FT-IR, UV/Vis, multinuclear NMR spectroscopy, and ESI-MS. The relative stabilities of the possible structural isomers were probed using dispersion-corrected DFT calculations for both polyoxometalate systems.

Original languageEnglish
Pages (from-to)8568-8572
Number of pages6
JournalAngewandte Chemie - International Edition
Volume56
Issue number29
DOIs
Publication statusPublished - 10 Jul 2017

Keywords

  • Microwave chemistry
  • Polyoxometalates
  • Solution dynamics
  • Spectroscopy
  • Structural reorganization

Cite this

Spillane, Samuel ; Sharma, Rupali ; Zavras, Athanasios ; Mulder, Roger ; Ohlin, Andy ; Goerigk, Lars ; O'Hair, Richard A J ; Ritchie, Chris. / Non-aqueous microwave-assisted syntheses of deca- and hexa-molybdovanadates. In: Angewandte Chemie - International Edition. 2017 ; Vol. 56, No. 29. pp. 8568-8572.
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Spillane, S, Sharma, R, Zavras, A, Mulder, R, Ohlin, A, Goerigk, L, O'Hair, RAJ & Ritchie, C 2017, 'Non-aqueous microwave-assisted syntheses of deca- and hexa-molybdovanadates', Angewandte Chemie - International Edition, vol. 56, no. 29, pp. 8568-8572. https://doi.org/10.1002/anie.201608589

Non-aqueous microwave-assisted syntheses of deca- and hexa-molybdovanadates. / Spillane, Samuel; Sharma, Rupali; Zavras, Athanasios; Mulder, Roger; Ohlin, Andy; Goerigk, Lars; O'Hair, Richard A J; Ritchie, Chris.

In: Angewandte Chemie - International Edition, Vol. 56, No. 29, 10.07.2017, p. 8568-8572.

Research output: Contribution to journalArticleResearchpeer-review

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