Nickel(0) catalysed additions of hydrogen cyanide to alkynes: Stereochemistry, mechanism, and preparative application

W. Roy Jackson; Craig G. Lovel

doi:10.1039/C39820001231

Nickel(0) catalysed additions of hydrogen cyanide to alkynes: Stereochemistry, mechanism, and preparative application

W. Roy Jackson, Craig G. Lovel

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

44 Citations (Scopus)

Abstract

The addition of hydrogen cyanide to both terminal and disubstituted acetylenes occurs with cis-stereospecificity in moderate to excellent yields when catalysed by a nickel(0) complex.

Original language	English
Pages (from-to)	1231-1232
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	21
DOIs	https://doi.org/10.1039/C39820001231
Publication status	Published - 1 Jan 1982

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10.1039/C39820001231

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Cite this

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title = "Nickel(0) catalysed additions of hydrogen cyanide to alkynes: Stereochemistry, mechanism, and preparative application",

abstract = "The addition of hydrogen cyanide to both terminal and disubstituted acetylenes occurs with cis-stereospecificity in moderate to excellent yields when catalysed by a nickel(0) complex.",

author = "Jackson, {W. Roy} and Lovel, {Craig G.}",

year = "1982",

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doi = "10.1039/C39820001231",

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AU - Lovel, Craig G.

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Y1 - 1982/1/1

N2 - The addition of hydrogen cyanide to both terminal and disubstituted acetylenes occurs with cis-stereospecificity in moderate to excellent yields when catalysed by a nickel(0) complex.

AB - The addition of hydrogen cyanide to both terminal and disubstituted acetylenes occurs with cis-stereospecificity in moderate to excellent yields when catalysed by a nickel(0) complex.

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