Nanosponge formation from organocatalytically synthesized poly(carbonate) copolymers

David M. Stevens; Sarah Tempelaar; Andrew P. Dove; Eva Harth

doi:10.1021/mz300179r

Nanosponge formation from organocatalytically synthesized poly(carbonate) copolymers

David M. Stevens, Sarah Tempelaar, Andrew P. Dove, Eva Harth

Research output: Contribution to journal › Article › Research › peer-review

54 Citations (Scopus)

Abstract

Advanced organocatalytic synthesis methods were employed to prepare linear poly(carbonate)s with control over functional group incorporation and molecular weight. Pendant allyl or epoxide groups served as reaction partners in thiol-ene click or epoxide-amine reactions with ethylene oxide-containing cross-linking groups to form a panel of six novel poly(carbonate) nanosponges with cross-linking densities ranging from 5, 10, and 20% via an intermolecular chain crosslinking approach.

Original language	English
Pages (from-to)	915-918
Number of pages	4
Journal	ACS Macro Letters
Volume	1
Issue number	7
DOIs	https://doi.org/10.1021/mz300179r
Publication status	Published - 2012
Externally published	Yes

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10.1021/mz300179r

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title = "Nanosponge formation from organocatalytically synthesized poly(carbonate) copolymers",

abstract = "Advanced organocatalytic synthesis methods were employed to prepare linear poly(carbonate)s with control over functional group incorporation and molecular weight. Pendant allyl or epoxide groups served as reaction partners in thiol-ene click or epoxide-amine reactions with ethylene oxide-containing cross-linking groups to form a panel of six novel poly(carbonate) nanosponges with cross-linking densities ranging from 5, 10, and 20% via an intermolecular chain crosslinking approach.",

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AU - Dove, Andrew P.

AU - Harth, Eva

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AB - Advanced organocatalytic synthesis methods were employed to prepare linear poly(carbonate)s with control over functional group incorporation and molecular weight. Pendant allyl or epoxide groups served as reaction partners in thiol-ene click or epoxide-amine reactions with ethylene oxide-containing cross-linking groups to form a panel of six novel poly(carbonate) nanosponges with cross-linking densities ranging from 5, 10, and 20% via an intermolecular chain crosslinking approach.

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Nanosponge formation from organocatalytically synthesized poly(carbonate) copolymers

Abstract

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