Nanocellulose-montmorillonite composites of low water vapour permeability

Uthpala M. Garusinghe, Swambabu Varanasi, Vikram S. Raghuwanshi, Gil Garnier, Warren Batchelor

Research output: Contribution to journalArticleResearchpeer-review

Abstract

A simple technique was developed to well disperse montmorillonite (MMT) into novel nanocellulose composites of varying MMT content (9.1–37.5 wt%). The objective was to develop nanocellulose-MMT composites of very low water vapour permeability (WVP) by increasing the composite tortuosity. The new composites are strong (strength-110 MPa), stiff (modulus-11 GPa) yet flexible. Scanning electron micrographs revealed MMT platelets to be uniformly distributed across and within the composite, creating a tortuous path restricting water molecules diffusion. WVP decreased by half, from 24.2 ± 2.7 g μm/m2 day kPa without MMT to 13.3 ± 2.0 g μm/m2 day kPa with only 16.7 wt% MMT. Further increasing the MMT content increased composite WVP, due to MMT aggregation. Two separate MMT dispersion methods were tested to break down MMT stacks and improve WVP by increasing MMT available surface area: (a) sonication, which worsened WVP, and (b) high pressure homogenization, which reduced WVP further to 6.33 ± 1.5 g μm/m2 day kPa with 23.1 wt% MMT. This is the lowest WVP reported in literature for nanocellulose-MMT composites. This study developed a recyclable composite of very low WVP. These thin, inexpensive, strong and flexible nanocellulose-MMT composites present a new and attractive option as recyclable/compostable packaging materials for large volume packing applications where water vapour protection is critical.

Original languageEnglish
Pages (from-to)233-241
Number of pages9
JournalColloids and Surfaces A: Physicochemical and Engineering Aspects
Volume540
DOIs
Publication statusPublished - 5 Mar 2018

Keywords

  • Composites
  • Montmorillonite (MMT)
  • Nanocellulose
  • Packaging
  • Water vapour permeability (WVP)

Cite this

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title = "Nanocellulose-montmorillonite composites of low water vapour permeability",
abstract = "A simple technique was developed to well disperse montmorillonite (MMT) into novel nanocellulose composites of varying MMT content (9.1–37.5 wt{\%}). The objective was to develop nanocellulose-MMT composites of very low water vapour permeability (WVP) by increasing the composite tortuosity. The new composites are strong (strength-110 MPa), stiff (modulus-11 GPa) yet flexible. Scanning electron micrographs revealed MMT platelets to be uniformly distributed across and within the composite, creating a tortuous path restricting water molecules diffusion. WVP decreased by half, from 24.2 ± 2.7 g μm/m2 day kPa without MMT to 13.3 ± 2.0 g μm/m2 day kPa with only 16.7 wt{\%} MMT. Further increasing the MMT content increased composite WVP, due to MMT aggregation. Two separate MMT dispersion methods were tested to break down MMT stacks and improve WVP by increasing MMT available surface area: (a) sonication, which worsened WVP, and (b) high pressure homogenization, which reduced WVP further to 6.33 ± 1.5 g μm/m2 day kPa with 23.1 wt{\%} MMT. This is the lowest WVP reported in literature for nanocellulose-MMT composites. This study developed a recyclable composite of very low WVP. These thin, inexpensive, strong and flexible nanocellulose-MMT composites present a new and attractive option as recyclable/compostable packaging materials for large volume packing applications where water vapour protection is critical.",
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Nanocellulose-montmorillonite composites of low water vapour permeability. / Garusinghe, Uthpala M.; Varanasi, Swambabu; Raghuwanshi, Vikram S.; Garnier, Gil; Batchelor, Warren.

In: Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 540, 05.03.2018, p. 233-241.

Research output: Contribution to journalArticleResearchpeer-review

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T1 - Nanocellulose-montmorillonite composites of low water vapour permeability

AU - Garusinghe, Uthpala M.

AU - Varanasi, Swambabu

AU - Raghuwanshi, Vikram S.

AU - Garnier, Gil

AU - Batchelor, Warren

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KW - Composites

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KW - Packaging

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