Multinuclear NMR study of the pressure dependence for carbonate exchange in the UO2(CO3)34-(aq) ion

Rene Johnson, Steven Harley, Christian Andre Ohlin, Adele Panasci, William Casey

Research output: Contribution to journalArticleResearchpeer-review

10 Citations (Scopus)

Abstract

PH shows the way: Rates of carbonate exchange by two pH-sensitive pathways between aqueous carbonate ion and UO2(CO3)34a??(aq) (see picture) are measured by high-pressure NMR. To accomplish this, a custom pulse sequence is employed to achieve selective inversion. Rates of chemical exchange are determined by modeling the return to equilibrium.
Original languageEnglish
Pages (from-to)2903 - 2906
Number of pages4
JournalChemPhysChem
Volume12
Issue number16
DOIs
Publication statusPublished - 2011

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