Monomeric tris(η2-pyrazolato)lanthanoid complexes with the bulky 3,5-di(tert-butyl)pyrazolato ligand

Joanna E. Cosgriff; Glen B. Deacon; Bryan M. Gatehouse; Holger Hemling; Herbert Schumann

doi:10.1002/anie.199308741

Monomeric tris(η2-pyrazolato)lanthanoid complexes with the bulky 3,5-di(tert-butyl)pyrazolato ligand

Joanna E. Cosgriff, Glen B. Deacon, Bryan M. Gatehouse, Holger Hemling, Herbert Schumann

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

50 Citations (Scopus)

Abstract

The reaction of lanthanoids, Hg(C6F5)2, and tBu2pz (pz = pyrazolate) in THF provided the first monomeric lanthanoid complexes of type 1 with solely chelating pz ligands. The structure on the right depicts the neodymium complex.

Original language	English
Pages (from-to)	874-875
Number of pages	2
Journal	Angewandte Chemie: International Edition in English
Volume	32
Issue number	6
DOIs	https://doi.org/10.1002/anie.199308741
Publication status	Published - Jun 1993

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title = "Monomeric tris(η2-pyrazolato)lanthanoid complexes with the bulky 3,5-di(tert-butyl)pyrazolato ligand",

abstract = "The reaction of lanthanoids, Hg(C6F5)2, and tBu2pz (pz = pyrazolate) in THF provided the first monomeric lanthanoid complexes of type 1 with solely chelating pz ligands. The structure on the right depicts the neodymium complex.",

author = "Cosgriff, {Joanna E.} and Deacon, {Glen B.} and Gatehouse, {Bryan M.} and Holger Hemling and Herbert Schumann",

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AU - Deacon, Glen B.

AU - Gatehouse, Bryan M.

AU - Hemling, Holger

AU - Schumann, Herbert

PY - 1993/6

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AB - The reaction of lanthanoids, Hg(C6F5)2, and tBu2pz (pz = pyrazolate) in THF provided the first monomeric lanthanoid complexes of type 1 with solely chelating pz ligands. The structure on the right depicts the neodymium complex.

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 6

ER -

Monomeric tris(η2-pyrazolato)lanthanoid complexes with the bulky 3,5-di(tert-butyl)pyrazolato ligand

Abstract

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