Modular inorganic polyoxometalate frameworks showing emergent properties: Redox alloys

Johannes Thiel; Chris Ritchie; Haralampos N. Miras; Carsten Streb; Scott G. Mitchell; Thomas Boyd; M. Nieves Corella Ochoa; Mali H. Rosnes; Jim McIver; De Liang Long; Leroy Cronin

doi:10.1002/anie.201002672

Modular inorganic polyoxometalate frameworks showing emergent properties: Redox alloys

Johannes Thiel, Chris Ritchie, Haralampos N. Miras, Carsten Streb, Scott G. Mitchell, Thomas Boyd, M. Nieves Corella Ochoa, Mali H. Rosnes, Jim McIver, De Liang Long, Leroy Cronin

Research output: Contribution to journal › Article › Research › peer-review

51 Citations (Scopus)

Abstract

Alloy, alloy: A pure cobalt-based Keggin network linked by W-O-Co interactions is "alloyed" with a pure manganese-based Keggin network, linked by W-O-Mn interactions. These isostructural alloys are solid solutions of the Co and Mn nets. The alloys are prepared by the stoichiometric mixing of the components of each discrete network, leading to a series of single-crystalline mixed transition-metal frameworks with novel redox properties.

Original language	English
Pages (from-to)	6984-6988
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	39
DOIs	https://doi.org/10.1002/anie.201002672
Publication status	Published - 17 Sept 2010
Externally published	Yes

Keywords

Alloys
Framework materials
Polyoxometalates
Redox chemistry

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10.1002/anie.201002672

Cite this

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T1 - Modular inorganic polyoxometalate frameworks showing emergent properties

T2 - Redox alloys

AU - Thiel, Johannes

AU - Ritchie, Chris

AU - Miras, Haralampos N.

AU - Streb, Carsten

AU - Mitchell, Scott G.

AU - Boyd, Thomas

AU - Ochoa, M. Nieves Corella

AU - Rosnes, Mali H.

AU - McIver, Jim

AU - Long, De Liang

AU - Cronin, Leroy

PY - 2010/9/17

Y1 - 2010/9/17

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KW - Alloys

KW - Framework materials

KW - Polyoxometalates

KW - Redox chemistry

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M3 - Article

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 39

ER -

Modular inorganic polyoxometalate frameworks showing emergent properties: Redox alloys

Abstract

Keywords

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