Abstract
The fluidity model of Hildebrand has been modified to account for changes in molecular diameter that occur near the melting point. We show that there is a similarity between the divergence from the fluidity equation and the increase in molecular diameter. Both these phenomena are noticeable only below a reduced temperature of 0.46. It is shown that if the changes in molecular volume are taken into account good agreement with experimental data is obtained.
| Original language | English |
|---|---|
| Pages (from-to) | 57-60 |
| Number of pages | 4 |
| Journal | The Chemical Engineering Journal |
| Volume | 16 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 1 Jan 1978 |
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