Mixed donor, phenanthroline photoactive MOFs with favourable CO2selectivity

Caitlin J. Setter; Michael B. Price; Luke Conte; Wolfgang Schmitt; Stuart R. Batten; Christopher Richardson; Matthew R. Hill; Ravichandar Babarao; Lauren K. MacReadie

doi:10.1039/d0cc05715k

Mixed donor, phenanthroline photoactive MOFs with favourable CO₂selectivity

Caitlin J. Setter, Michael B. Price, Luke Conte, Wolfgang Schmitt, Stuart R. Batten, Christopher Richardson, Matthew R. Hill, Ravichandar Babarao, Lauren K. MacReadie

Research output: Contribution to journal › Article › Research › peer-review

6 Citations (Scopus)

Abstract

Mixed donor phenanthroline-carboxylate linkers were combined with MnII or ZnII to form photoactive MOFs with large pore apertures. The MOFs display high CO2 adsorption capacities, which consequently causes structural framework flexibility, and align with favorable metrics for selective CO2 capture. The photophysical properties of the MOFs were investigated, with the MnII MOF giving rise to short triplet LMCT lifetimes.

Original language	English
Pages (from-to)	13377-13380
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	87
DOIs	https://doi.org/10.1039/d0cc05715k
Publication status	Published - 11 Nov 2020

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10.1039/d0cc05715kLicence: CC BY

Cite this

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abstract = "Mixed donor phenanthroline-carboxylate linkers were combined with MnII or ZnII to form photoactive MOFs with large pore apertures. The MOFs display high CO2 adsorption capacities, which consequently causes structural framework flexibility, and align with favorable metrics for selective CO2 capture. The photophysical properties of the MOFs were investigated, with the MnII MOF giving rise to short triplet LMCT lifetimes. ",

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AU - Setter, Caitlin J.

AU - Price, Michael B.

AU - Conte, Luke

AU - Schmitt, Wolfgang

AU - Batten, Stuart R.

AU - Richardson, Christopher

AU - Hill, Matthew R.

AU - Babarao, Ravichandar

AU - MacReadie, Lauren K.

PY - 2020/11/11

Y1 - 2020/11/11

N2 - Mixed donor phenanthroline-carboxylate linkers were combined with MnII or ZnII to form photoactive MOFs with large pore apertures. The MOFs display high CO2 adsorption capacities, which consequently causes structural framework flexibility, and align with favorable metrics for selective CO2 capture. The photophysical properties of the MOFs were investigated, with the MnII MOF giving rise to short triplet LMCT lifetimes.

AB - Mixed donor phenanthroline-carboxylate linkers were combined with MnII or ZnII to form photoactive MOFs with large pore apertures. The MOFs display high CO2 adsorption capacities, which consequently causes structural framework flexibility, and align with favorable metrics for selective CO2 capture. The photophysical properties of the MOFs were investigated, with the MnII MOF giving rise to short triplet LMCT lifetimes.

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JO - Chemical Communications

JF - Chemical Communications

IS - 87

ER -

Mixed donor, phenanthroline photoactive MOFs with favourable CO₂selectivity

Abstract

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Australian Synchrotron

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Mixed donor, phenanthroline photoactive MOFs with favourable CO2selectivity

Abstract

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Australian Synchrotron

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Mixed donor, phenanthroline photoactive MOFs with favourable CO₂selectivity