Mineralogy and geochemistry of pattern formation in print stone from the Pilbara, Australia

'Print stone' is an iron-banded siltstone from the Pilbara Province of Western Australia that bears partial resemblance to iconic East Kimberley 'zebra rock' in both pattern morphology and mineralogical composition. Using a combination of mineralogy and elemental geochemistry, this study examines the mechanisms underlying the formation of periodic iron-oxide banding in print stone. We demonstrate that print stone patterns likely arose from the periodic deposition of hydrothermal pyrite during the early Paleoproterozoic, as evidenced by the distinctive cuboid morphology of the hematite pigment, the deposition of iron oxides along fluid-transport pathways, the presence of extensive hydrothermal pyrite elsewhere in the formation, and the presence of a positive europium anomaly. Through spatial analysis of the iron-oxide banding, we further show that print stone adheres to the Liesegang spacing law with a spacing coefficient of 0.018. This suggests that the periodic deposition of pyrite in print stone arose due to the Liesegang phenomenon, which was likely triggered by the infiltration of near-neutral, sulfidic hydrothermal fluids into a ferruginous, feldspathic shale. Altogether, the findings of this study demonstrate the ability for iron-oxide Liesegang bands to develop in hydrothermal systems, providing additional insight into the mechanisms underlying the formation of East Kimberley zebra rock and other banded geological material.