Mild and efficient functionalization of hydrogen-terminated Si(111) via sonochemical activated hydrosilylation

Yu Lin Zhong; Steven L Bernasek

doi:10.1021/ja2020839

Mild and efficient functionalization of hydrogen-terminated Si(111) via sonochemical activated hydrosilylation

Yu Lin Zhong, Steven L Bernasek

Research output: Contribution to journal › Article › Research › peer-review

37 Citations (Scopus)

Abstract

Efficient chemical functionalization of hydrogen-terminated Si(1 1 1) with simple and bifunctional 1-alkenes was achieved via novel sonochemical activated hydrosilylation, utilizing just a simple ultrasonic bath. It is an extremely mild method that allows the specific attachment of unprotected bifunctional alkenes such as undecenol, undecylenic acid, and even a heat/UV-sensitive alkene, bearing an activated leaving group (N-succinimidyl undecylenate), without suffering any degradation.

Original language	English
Pages (from-to)	8118-8121
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	133
Issue number	21
DOIs	https://doi.org/10.1021/ja2020839
Publication status	Published - 2011
Externally published	Yes

Access to Document

10.1021/ja2020839

Cite this

@article{e49901a4d1c24767b807bf783dfa06ab,

title = "Mild and efficient functionalization of hydrogen-terminated Si(111) via sonochemical activated hydrosilylation",

abstract = "Efficient chemical functionalization of hydrogen-terminated Si(1 1 1) with simple and bifunctional 1-alkenes was achieved via novel sonochemical activated hydrosilylation, utilizing just a simple ultrasonic bath. It is an extremely mild method that allows the specific attachment of unprotected bifunctional alkenes such as undecenol, undecylenic acid, and even a heat/UV-sensitive alkene, bearing an activated leaving group (N-succinimidyl undecylenate), without suffering any degradation.",

author = "Zhong, {Yu Lin} and Bernasek, {Steven L}",

year = "2011",

doi = "10.1021/ja2020839",

language = "English",

volume = "133",

pages = "8118--8121",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "21",

}

TY - JOUR

T1 - Mild and efficient functionalization of hydrogen-terminated Si(111) via sonochemical activated hydrosilylation

AU - Zhong, Yu Lin

AU - Bernasek, Steven L

PY - 2011

Y1 - 2011

N2 - Efficient chemical functionalization of hydrogen-terminated Si(1 1 1) with simple and bifunctional 1-alkenes was achieved via novel sonochemical activated hydrosilylation, utilizing just a simple ultrasonic bath. It is an extremely mild method that allows the specific attachment of unprotected bifunctional alkenes such as undecenol, undecylenic acid, and even a heat/UV-sensitive alkene, bearing an activated leaving group (N-succinimidyl undecylenate), without suffering any degradation.

AB - Efficient chemical functionalization of hydrogen-terminated Si(1 1 1) with simple and bifunctional 1-alkenes was achieved via novel sonochemical activated hydrosilylation, utilizing just a simple ultrasonic bath. It is an extremely mild method that allows the specific attachment of unprotected bifunctional alkenes such as undecenol, undecylenic acid, and even a heat/UV-sensitive alkene, bearing an activated leaving group (N-succinimidyl undecylenate), without suffering any degradation.

U2 - 10.1021/ja2020839

DO - 10.1021/ja2020839

M3 - Article

SN - 0002-7863

VL - 133

SP - 8118

EP - 8121

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 21

ER -