Skip to main navigation Skip to search Skip to main content

Metal-Organic Frameworks (MOFs) as potential hybrid ferroelectric materials

Research output: Chapter in Book/Report/Conference proceedingChapter (Book)Otherpeer-review

Abstract

This chapter presents new findings of intrinsic and induced ferroelectricity in Metal-Organic Frameworks (MOFs) with a polar system, capable of forming an electronic structure in an asymmetric lattice. Multiple experimental techniques and simulation methods are reviewed in detail. The characteristics of ferroelectrics such as discontinuity in temperature-dependent dielectric constant, polarization hysteresis loops, etc. have been observed from several MOF large crystals and crystalline powders. A relationship between polarization and bond polarity for MOFs has been established. In addition, we emphasize the significance of mechanical strength of MOFs in real applications. This chapter reviews MOF materials for energy storage and utilization, aiming to provide an insight into the design of novel MOF-based ferroelectrics.

Original languageEnglish
Title of host publicationLayered Materials for Energy Storage and Conversion
EditorsDongsheng Geng, Yuan Cheng, Gang Zhang
Place of PublicationLondon UK
PublisherThe Royal Society of Chemistry
Chapter7
Pages197-244
Number of pages48
ISBN (Electronic)9781788016193, 9781788017381
ISBN (Print)9781788014267
DOIs
Publication statusPublished - 2019
Externally publishedYes

Publication series

NameSmart Materials
PublisherThe Royal Society of Chemistry
Volume34
ISSN (Print)2046-0066
ISSN (Electronic)2046-0074

Cite this