Metal organic framework based catalysts for CO2 conversion

James W. Maina, Cristina Pozo-Gonzalo, Lingxue Kong, Jurg Schutz, Matthew Hill, Ludovic F. Dumee

Research output: Contribution to journalReview ArticleResearchpeer-review

168 Citations (Scopus)

Abstract

Metal organic frameworks (MOFs) are hybrid crystalline materials, exhibiting high specific surface areas, controllable pore sizes and surface chemistry. These properties have made MOFs attractive for a wide range of applications including gas separation, gas storage, sensing, drug delivery and catalysis. This review focuses on recent progress in the application of MOF materials as catalysts for CO2 conversion through chemical fixation, photocatalysis and electrocatalysis. In particular, this review discusses the co-relationship between the physicochemical properties of MOF materials including their catalytic performance as well as their stability and recyclability under different reaction conditions, relevant to CO2 conversion. Current modification techniques for improving MOF performance are highlighted along with the recent understanding of their electronic properties. The limitations of MOF based catalysts are also discussed and potential routes for improvement are suggested.
Original languageEnglish
Article number345
Pages (from-to)345-361
Number of pages17
JournalMaterials Horizons
Volume4
Issue number3
DOIs
Publication statusPublished - 28 Feb 2017
Externally publishedYes

Cite this

Maina, J. W., Pozo-Gonzalo, C., Kong, L., Schutz, J., Hill, M., & Dumee, L. F. (2017). Metal organic framework based catalysts for CO2 conversion. Materials Horizons, 4(3), 345-361. [345]. https://doi.org/10.1039/c6mh00484a