Metal Acetylide Elimination

The Key Step in the Cascade Decomposition and Transformation of Metalated Propargylamines

Research output: Contribution to journalArticleResearchpeer-review

1 Citation (Scopus)

Abstract

Metal acetylide elimination facilitates a novel one-pot cascade metalation and elimination/addition route to a series of unsymmetrical secondary amines from the reaction of secondary propargylamines with organometallic reagents. Spectroscopic evidence suggests a dimetalated amido intermediate rather than an allene.

Original languageEnglish
Pages (from-to)1225-1228
Number of pages4
JournalOrganometallics
Volume37
Issue number8
DOIs
Publication statusPublished - 23 Apr 2018

Cite this

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title = "Metal Acetylide Elimination: The Key Step in the Cascade Decomposition and Transformation of Metalated Propargylamines",
abstract = "Metal acetylide elimination facilitates a novel one-pot cascade metalation and elimination/addition route to a series of unsymmetrical secondary amines from the reaction of secondary propargylamines with organometallic reagents. Spectroscopic evidence suggests a dimetalated amido intermediate rather than an allene.",
author = "Flynn, {Matthew T.} and Blair, {Victoria L.} and Andrews, {Philip C.}",
year = "2018",
month = "4",
day = "23",
doi = "10.1021/acs.organomet.8b00047",
language = "English",
volume = "37",
pages = "1225--1228",
journal = "Organometallics",
issn = "0276-7333",
publisher = "American Chemical Society",
number = "8",

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Metal Acetylide Elimination : The Key Step in the Cascade Decomposition and Transformation of Metalated Propargylamines. / Flynn, Matthew T.; Blair, Victoria L.; Andrews, Philip C.

In: Organometallics, Vol. 37, No. 8, 23.04.2018, p. 1225-1228.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Metal Acetylide Elimination

T2 - The Key Step in the Cascade Decomposition and Transformation of Metalated Propargylamines

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AU - Blair, Victoria L.

AU - Andrews, Philip C.

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AB - Metal acetylide elimination facilitates a novel one-pot cascade metalation and elimination/addition route to a series of unsymmetrical secondary amines from the reaction of secondary propargylamines with organometallic reagents. Spectroscopic evidence suggests a dimetalated amido intermediate rather than an allene.

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JO - Organometallics

JF - Organometallics

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