Metal Acetylide Elimination: The Key Step in the Cascade Decomposition and Transformation of Metalated Propargylamines

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Abstract

Metal acetylide elimination facilitates a novel one-pot cascade metalation and elimination/addition route to a series of unsymmetrical secondary amines from the reaction of secondary propargylamines with organometallic reagents. Spectroscopic evidence suggests a dimetalated amido intermediate rather than an allene.

Original languageEnglish
Pages (from-to)1225-1228
Number of pages4
JournalOrganometallics
Volume37
Issue number8
DOIs
Publication statusPublished - 23 Apr 2018

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