Luminescent sensing of a new 8-connected topological metal-organic framework

Yu Wu, Weiping Wu, Like Zou, Jianshen Feng, Chuying Gu, Baohong Li, Stuart R Batten, Reena Yadav, Abhinav Kumar

Research output: Contribution to journalArticleResearchpeer-review

7 Citations (Scopus)

Abstract

A new metal-organic framework having formula {[Cd3(H2O)(L)2][Cd(im)3(H2O)2]·3 H2O} (H4L = 5-bis(4-carbonylbenzyl)aminoisophthalic acid and im = imidazole) (1) has been synthesized. X-ray investigation reveals that 1 is rare 4,4,8-connected (46)(45 · 6)(411 · 615 · 82) topology. The present work indicates that 1 could be a prospective candidate for developing novel luminescence sensors for the selective sensing of nitrobenzene which can be used as a precursor for explosives. Furthermore, the luminescent property of 1 in different solvents analytes as well as nitrobenzene have been investigated and the observed quenching in fluorescence have been corroborated by theoretical calculations.

Original languageEnglish
Pages (from-to)160-163
Number of pages4
JournalInorganic Chemistry Communication
Volume70
DOIs
Publication statusPublished - 1 Aug 2016

Keywords

  • Luminescent sensing
  • Topology, DFT

Cite this

Wu, Yu ; Wu, Weiping ; Zou, Like ; Feng, Jianshen ; Gu, Chuying ; Li, Baohong ; Batten, Stuart R ; Yadav, Reena ; Kumar, Abhinav. / Luminescent sensing of a new 8-connected topological metal-organic framework. In: Inorganic Chemistry Communication. 2016 ; Vol. 70. pp. 160-163.
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Luminescent sensing of a new 8-connected topological metal-organic framework. / Wu, Yu; Wu, Weiping; Zou, Like; Feng, Jianshen; Gu, Chuying; Li, Baohong; Batten, Stuart R; Yadav, Reena; Kumar, Abhinav.

In: Inorganic Chemistry Communication, Vol. 70, 01.08.2016, p. 160-163.

Research output: Contribution to journalArticleResearchpeer-review

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AU - Wu, Yu

AU - Wu, Weiping

AU - Zou, Like

AU - Feng, Jianshen

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AU - Batten, Stuart R

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AU - Kumar, Abhinav

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