Luminescent hyperbranched polymers: combining thiol-yne chemistry with gold-mediated C-H bond activation

Dominik Konkolewicz; Sylvain Gaillard; Andrew West; Yuen Cheng; Angus Gray-Weale; Timothy Schmidt; Steven Nolan; Sebastien Perrier

doi:10.1021/om200103f

Luminescent hyperbranched polymers: combining thiol-yne chemistry with gold-mediated C-H bond activation

Dominik Konkolewicz, Sylvain Gaillard, Andrew West, Yuen Cheng, Angus Gray-Weale, Timothy Schmidt, Steven Nolan, Sebastien Perrier

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

42 Citations (Scopus)

Abstract

A highly efficient and straightforward synthetic method, leading to the formation of a luminescent hyper-branched polymer, is described. The simple polymer functionalization step takes advantage of the reactivity of relatively acidic alkyne C-H bonds with a basic [Au(NHC)(OH)] (NHC = N-heterocyclic carbene) synthon

Original language	English
Pages (from-to)	1315 - 1318
Number of pages	4
Journal	Organometallics
Volume	30
Issue number	6
DOIs	https://doi.org/10.1021/om200103f
Publication status	Published - 2011

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10.1021/om200103f

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title = "Luminescent hyperbranched polymers: combining thiol-yne chemistry with gold-mediated C-H bond activation",

abstract = "A highly efficient and straightforward synthetic method, leading to the formation of a luminescent hyper-branched polymer, is described. The simple polymer functionalization step takes advantage of the reactivity of relatively acidic alkyne C-H bonds with a basic [Au(NHC)(OH)] (NHC = N-heterocyclic carbene) synthon",

author = "Dominik Konkolewicz and Sylvain Gaillard and Andrew West and Yuen Cheng and Angus Gray-Weale and Timothy Schmidt and Steven Nolan and Sebastien Perrier",

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T1 - Luminescent hyperbranched polymers: combining thiol-yne chemistry with gold-mediated C-H bond activation

AU - Konkolewicz, Dominik

AU - Gaillard, Sylvain

AU - West, Andrew

AU - Cheng, Yuen

AU - Gray-Weale, Angus

AU - Schmidt, Timothy

AU - Nolan, Steven

AU - Perrier, Sebastien

PY - 2011

Y1 - 2011

N2 - A highly efficient and straightforward synthetic method, leading to the formation of a luminescent hyper-branched polymer, is described. The simple polymer functionalization step takes advantage of the reactivity of relatively acidic alkyne C-H bonds with a basic [Au(NHC)(OH)] (NHC = N-heterocyclic carbene) synthon

AB - A highly efficient and straightforward synthetic method, leading to the formation of a luminescent hyper-branched polymer, is described. The simple polymer functionalization step takes advantage of the reactivity of relatively acidic alkyne C-H bonds with a basic [Au(NHC)(OH)] (NHC = N-heterocyclic carbene) synthon

UR - http://pubs.acs.org/doi/pdfplus/10.1021/om200103f

U2 - 10.1021/om200103f

DO - 10.1021/om200103f

M3 - Article

SN - 0276-7333

VL - 30

SP - 1315

EP - 1318

JO - Organometallics

JF - Organometallics

IS - 6

ER -

Luminescent hyperbranched polymers: combining thiol-yne chemistry with gold-mediated C-H bond activation

Abstract

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