Luminescence sensing of an unusual tetranodal 3-connected topology of Cu(I)-MOF

Yu Wu, Jun Wang, Like Zou, Fengchun Zeng, Jianshen Feng, Xiren Wu, Jingwen Xu, Stuart R. Batten

Research output: Contribution to journalArticleOtherpeer-review

5 Citations (Scopus)

Abstract

A new Cu(I)-based complex with chemical formulae [Cu4Cl0.24(CN)3.76(L)] (1), (L = 1,3,5-tris(1-imidazolyl) benzene) has been synthesized and structurally characterized. Compound 1 shows an unusual tetranodal 3-connected topology and is self-penetrating - 0-membered shortest circuits. It shows that 1 can work as highly sensitive sensors to Cu2+ and nitrobenzene (NB) explosive by luminescent quenching. This study shows that 1 could be a useful luminescent sensor for metal ions and organic small molecules.

Original languageEnglish
Pages (from-to)13-15
Number of pages3
JournalInorganic Chemistry Communication
Volume69
DOIs
Publication statusPublished - 1 Jul 2016

Keywords

  • Luminescence
  • Self-penetration
  • Supramolecular architecture

Cite this

Wu, Yu ; Wang, Jun ; Zou, Like ; Zeng, Fengchun ; Feng, Jianshen ; Wu, Xiren ; Xu, Jingwen ; Batten, Stuart R. / Luminescence sensing of an unusual tetranodal 3-connected topology of Cu(I)-MOF. In: Inorganic Chemistry Communication. 2016 ; Vol. 69. pp. 13-15.
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abstract = "A new Cu(I)-based complex with chemical formulae [Cu4Cl0.24(CN)3.76(L)] (1), (L = 1,3,5-tris(1-imidazolyl) benzene) has been synthesized and structurally characterized. Compound 1 shows an unusual tetranodal 3-connected topology and is self-penetrating - 0-membered shortest circuits. It shows that 1 can work as highly sensitive sensors to Cu2+ and nitrobenzene (NB) explosive by luminescent quenching. This study shows that 1 could be a useful luminescent sensor for metal ions and organic small molecules.",
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author = "Yu Wu and Jun Wang and Like Zou and Fengchun Zeng and Jianshen Feng and Xiren Wu and Jingwen Xu and Batten, {Stuart R.}",
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Luminescence sensing of an unusual tetranodal 3-connected topology of Cu(I)-MOF. / Wu, Yu; Wang, Jun; Zou, Like; Zeng, Fengchun; Feng, Jianshen; Wu, Xiren; Xu, Jingwen; Batten, Stuart R.

In: Inorganic Chemistry Communication, Vol. 69, 01.07.2016, p. 13-15.

Research output: Contribution to journalArticleOtherpeer-review

TY - JOUR

T1 - Luminescence sensing of an unusual tetranodal 3-connected topology of Cu(I)-MOF

AU - Wu, Yu

AU - Wang, Jun

AU - Zou, Like

AU - Zeng, Fengchun

AU - Feng, Jianshen

AU - Wu, Xiren

AU - Xu, Jingwen

AU - Batten, Stuart R.

PY - 2016/7/1

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N2 - A new Cu(I)-based complex with chemical formulae [Cu4Cl0.24(CN)3.76(L)] (1), (L = 1,3,5-tris(1-imidazolyl) benzene) has been synthesized and structurally characterized. Compound 1 shows an unusual tetranodal 3-connected topology and is self-penetrating - 0-membered shortest circuits. It shows that 1 can work as highly sensitive sensors to Cu2+ and nitrobenzene (NB) explosive by luminescent quenching. This study shows that 1 could be a useful luminescent sensor for metal ions and organic small molecules.

AB - A new Cu(I)-based complex with chemical formulae [Cu4Cl0.24(CN)3.76(L)] (1), (L = 1,3,5-tris(1-imidazolyl) benzene) has been synthesized and structurally characterized. Compound 1 shows an unusual tetranodal 3-connected topology and is self-penetrating - 0-membered shortest circuits. It shows that 1 can work as highly sensitive sensors to Cu2+ and nitrobenzene (NB) explosive by luminescent quenching. This study shows that 1 could be a useful luminescent sensor for metal ions and organic small molecules.

KW - Luminescence

KW - Self-penetration

KW - Supramolecular architecture

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JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

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