Luminescence sensing of an unusual tetranodal 3-connected topology of Cu(I)-MOF

Yu Wu; Jun Wang; Like Zou; Fengchun Zeng; Jianshen Feng; Xiren Wu; Jingwen Xu; Stuart R. Batten

doi:10.1016/j.inoche.2016.04.018

Luminescence sensing of an unusual tetranodal 3-connected topology of Cu(I)-MOF

Yu Wu, Jun Wang, Like Zou, Fengchun Zeng, Jianshen Feng, Xiren Wu, Jingwen Xu, Stuart R. Batten

School of Chemistry

Research output: Contribution to journal › Article › Other › peer-review

8 Citations (Scopus)

Abstract

A new Cu(I)-based complex with chemical formulae [Cu₄Cl_0.24(CN)_3.76(L)] (1), (L = 1,3,5-tris(1-imidazolyl) benzene) has been synthesized and structurally characterized. Compound 1 shows an unusual tetranodal 3-connected topology and is self-penetrating - 0-membered shortest circuits. It shows that 1 can work as highly sensitive sensors to Cu²⁺ and nitrobenzene (NB) explosive by luminescent quenching. This study shows that 1 could be a useful luminescent sensor for metal ions and organic small molecules.

Original language	English
Pages (from-to)	13-15
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	69
DOIs	https://doi.org/10.1016/j.inoche.2016.04.018
Publication status	Published - 1 Jul 2016

Keywords

Luminescence
Self-penetration
Supramolecular architecture

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10.1016/j.inoche.2016.04.018

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title = "Luminescence sensing of an unusual tetranodal 3-connected topology of Cu(I)-MOF",

abstract = "A new Cu(I)-based complex with chemical formulae [Cu4Cl0.24(CN)3.76(L)] (1), (L = 1,3,5-tris(1-imidazolyl) benzene) has been synthesized and structurally characterized. Compound 1 shows an unusual tetranodal 3-connected topology and is self-penetrating - 0-membered shortest circuits. It shows that 1 can work as highly sensitive sensors to Cu2+ and nitrobenzene (NB) explosive by luminescent quenching. This study shows that 1 could be a useful luminescent sensor for metal ions and organic small molecules.",

keywords = "Luminescence, Self-penetration, Supramolecular architecture",

author = "Yu Wu and Jun Wang and Like Zou and Fengchun Zeng and Jianshen Feng and Xiren Wu and Jingwen Xu and Batten, {Stuart R.}",

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doi = "10.1016/j.inoche.2016.04.018",

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journal = "Inorganic Chemistry Communications",

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T1 - Luminescence sensing of an unusual tetranodal 3-connected topology of Cu(I)-MOF

AU - Wu, Yu

AU - Wang, Jun

AU - Zou, Like

AU - Zeng, Fengchun

AU - Feng, Jianshen

AU - Wu, Xiren

AU - Xu, Jingwen

AU - Batten, Stuart R.

PY - 2016/7/1

Y1 - 2016/7/1

N2 - A new Cu(I)-based complex with chemical formulae [Cu4Cl0.24(CN)3.76(L)] (1), (L = 1,3,5-tris(1-imidazolyl) benzene) has been synthesized and structurally characterized. Compound 1 shows an unusual tetranodal 3-connected topology and is self-penetrating - 0-membered shortest circuits. It shows that 1 can work as highly sensitive sensors to Cu2+ and nitrobenzene (NB) explosive by luminescent quenching. This study shows that 1 could be a useful luminescent sensor for metal ions and organic small molecules.

AB - A new Cu(I)-based complex with chemical formulae [Cu4Cl0.24(CN)3.76(L)] (1), (L = 1,3,5-tris(1-imidazolyl) benzene) has been synthesized and structurally characterized. Compound 1 shows an unusual tetranodal 3-connected topology and is self-penetrating - 0-membered shortest circuits. It shows that 1 can work as highly sensitive sensors to Cu2+ and nitrobenzene (NB) explosive by luminescent quenching. This study shows that 1 could be a useful luminescent sensor for metal ions and organic small molecules.

KW - Luminescence

KW - Self-penetration

KW - Supramolecular architecture

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DO - 10.1016/j.inoche.2016.04.018

M3 - Article

AN - SCOPUS:84966297193

SN - 1387-7003

VL - 69

SP - 13

EP - 15

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Luminescence sensing of an unusual tetranodal 3-connected topology of Cu(I)-MOF

Abstract

Keywords

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