Lithium diamidodihydridoaluminates: Bimetallic cooperativity in catalytic hydroboration and metallation applications

Victoria A. Pollard; Samantha A. Orr; Ross McLellan; Alan R. Kennedy; Eva Hevia; Robert E. Mulvey

doi:10.1039/c7cc08214b

Lithium diamidodihydridoaluminates: Bimetallic cooperativity in catalytic hydroboration and metallation applications

Victoria A. Pollard, Samantha A. Orr, Ross McLellan, Alan R. Kennedy, Eva Hevia, Robert E. Mulvey

Research output: Contribution to journal › Article › Research › peer-review

112 Citations (Scopus)

Abstract

Cooperativity between the Li and Al centres is implicated in catalytic hydroboration reactions of aldehydes and ketones with pinacolborane via heteroleptic lithium diamidodihydridoaluminates. In addition to implementing hydroalumination, these versatile heteroleptic ates can also perform as amido bases as illustrated with an acidic triazole.

Original language	English
Pages (from-to)	1233-1236
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	10
DOIs	https://doi.org/10.1039/c7cc08214b
Publication status	Published - 1 Jan 2018
Externally published	Yes

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title = "Lithium diamidodihydridoaluminates: Bimetallic cooperativity in catalytic hydroboration and metallation applications",

abstract = "Cooperativity between the Li and Al centres is implicated in catalytic hydroboration reactions of aldehydes and ketones with pinacolborane via heteroleptic lithium diamidodihydridoaluminates. In addition to implementing hydroalumination, these versatile heteroleptic ates can also perform as amido bases as illustrated with an acidic triazole.",

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T2 - Bimetallic cooperativity in catalytic hydroboration and metallation applications

AU - Pollard, Victoria A.

AU - Orr, Samantha A.

AU - McLellan, Ross

AU - Kennedy, Alan R.

AU - Hevia, Eva

AU - Mulvey, Robert E.

PY - 2018/1/1

Y1 - 2018/1/1

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AB - Cooperativity between the Li and Al centres is implicated in catalytic hydroboration reactions of aldehydes and ketones with pinacolborane via heteroleptic lithium diamidodihydridoaluminates. In addition to implementing hydroalumination, these versatile heteroleptic ates can also perform as amido bases as illustrated with an acidic triazole.

UR - https://www.scopus.com/pages/publications/85041598099

U2 - 10.1039/c7cc08214b

DO - 10.1039/c7cc08214b

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JO - Chemical Communications

JF - Chemical Communications

IS - 10

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Lithium diamidodihydridoaluminates: Bimetallic cooperativity in catalytic hydroboration and metallation applications

Abstract

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